Dinuclear nickel(ii) pivalate with μ-AQUA and DI-μ-Pivalato bridges showing a ferromagnetic interaction

Mikuriya Masahiro; Schumacher Melissa; Kawano Chinatsu; Akihara Takahiro; Ono Kenta; Yoshioka Daisuke; Sakiyama Hiroshi; Handa Makoto

Conţinutul numărului revistei

Articolul precedent

Articolul urmator

1034

Ultima descărcare din IBN:
2023-06-01 14:41

Căutarea după subiecte
similare conform CZU

546-3+544.1+66 (1)

Chimie anorganică (450)

Structura chimică a materiei (98)

Tehnologie chimică. Industrii chimice și înrudite (1502)

SM ISO690:2012

MIKURIYA, Masahiro, SCHUMACHER, Melissa, KAWANO, Chinatsu, AKIHARA, Takahiro, ONO, Kenta, YOSHIOKA, Daisuke, SAKIYAMA, Hiroshi, HANDA, Makoto. Dinuclear nickel(ii) pivalate with μ-AQUA and DI-μ-Pivalato bridges showing a ferromagnetic interaction. In: Chemistry Journal of Moldova, 2014, nr. 2(9), pp. 62-66. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2014.09(2).09

EXPORT metadate:
Google Scholar
Crossref
CERIF

DataCite
Dublin Core

Chemistry Journal of Moldova

Numărul 2(9) / 2014 / ISSN 1857-1727 /ISSNe 2345-1688

Dinuclear nickel(ii) pivalate with μ-AQUA and DI-μ-Pivalato bridges showing a ferromagnetic interaction

DOI:https://doi.org/10.19261/cjm.2014.09(2).09

CZU: 546-3+544.1+66

Pag. 62-66

Mikuriya Masahiro¹, Schumacher Melissa¹, Kawano Chinatsu¹, Akihara Takahiro¹, Ono Kenta¹, Yoshioka Daisuke¹, Sakiyama Hiroshi², Handa Makoto³

¹ Kwansei Gakuin University,
² Yamagata University,
³ Shimane University

Disponibil în IBN: 16 martie 2015

Descarcă PDF

Rezumat

Abstract. Dinuclear nickel(II) complex, [Ni2{O2CC(CH3)3}4(OH2){HO2CC(CH3)3}4] (1), was synthesized and characterized by elemental analysis, IR and UV-Vis-NIR spectroscopy, and temperature dependence of magnetic susceptibilities (4.5—300 K). Single-crystal X-ray crystallography revealed a dinuclear core with μ-aqua and di-μ-pivalato bridges having monodentate pivalato and monodentate pivalic acid molecules. Magnetic data analysis showed a ferromagnetic interactions between the two nickel atoms with g = 2.251, J = 2.78 cm−1, D = 3.75 cm–1, and tip = 184 x 10–6 cm3 mol–1; g = 2.253, J = 2.73 cm−1, D = –3.26 cm–1, and tip = 176 x 10–6 cm3 mol–1.

Cuvinte-cheie
nickel complex, dinuclear complex, ferromagnetic interaction, magnetic property

Crossref XML Export

<?xml version='1.0' encoding='utf-8'?>
<doi_batch version='4.3.7' xmlns='http://www.crossref.org/schema/4.3.7' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.crossref.org/schema/4.3.7 http://www.crossref.org/schema/deposit/crossref4.3.7.xsd'>
<head>
<doi_batch_id>ibn-35086</doi_batch_id>
<timestamp>1714191894</timestamp>
<depositor>
<depositor_name>Information Society Development Instiute, Republic of Moldova</depositor_name>
<email_address>idsi@asm.md</email_address>
</depositor>
<registrant>Institutul de Chimie al AŞM</registrant>
</head>
<body>
<journal>
<journal_metadata>
<full_title>Chemistry Journal of Moldova</full_title>
<issn media_type='print'>18571727</issn>
<doi_data>
<doi>10.19261</doi>
<resource>http://www.crossref.org/</resource>
</doi_data>
</journal_metadata>
<journal_issue>
<publication_date media_type='print'>
<year>2014</year>
</publication_date>
<issue>2(9)</issue>
</journal_issue>
<journal_article publication_type='full_text'><titles>
<title>Dinuclear nickel(ii) pivalate with μ-AQUA and DI-μ-Pivalato bridges showing a ferromagnetic interaction</title>
</titles>
<contributors>
<person_name sequence='first' contributor_role='author'>
<given_name>Masahiro</given_name>
<surname>Mikuriya</surname>
</person_name>
<person_name sequence='additional' contributor_role='author'>
<given_name>Melissa</given_name>
<surname>Schumacher</surname>
</person_name>
<person_name sequence='additional' contributor_role='author'>
<given_name>Chinatsu</given_name>
<surname>Kawano</surname>
</person_name>
<person_name sequence='additional' contributor_role='author'>
<given_name>Takahiro</given_name>
<surname>Akihara</surname>
</person_name>
<person_name sequence='additional' contributor_role='author'>
<given_name>Kenta</given_name>
<surname>Ono</surname>
</person_name>
<person_name sequence='additional' contributor_role='author'>
<given_name>Daisuke</given_name>
<surname>Yoshioka</surname>
</person_name>
<person_name sequence='additional' contributor_role='author'>
<given_name>Hiroshi</given_name>
<surname>Sakiyama</surname>
</person_name>
<person_name sequence='additional' contributor_role='author'>
<given_name>Makoto</given_name>
<surname>Handa</surname>
</person_name>
</contributors>
<publication_date media_type='print'>
<year>2014</year>
</publication_date>
<pages>
<first_page>62</first_page>
<last_page>66</last_page>
</pages>
<doi_data>
<doi>10.19261/cjm.2014.09(2).09</doi>
<resource>http://www.crossref.org/</resource>
</doi_data>
</journal_article>
</journal>
</body>
</doi_batch>