The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4&prime;-dimethyl-2,2&prime;-bispyridil and 2,2&prime;-bispyrimidine)

Madalan Augustin M.; Melnik E.; Kravtsov Victor; Simonov Yurii A.; Schmidtmann Marc; Muller Achim; Andruh Marius

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MADALAN, Augustin M., MELNIK, E., KRAVTSOV, Victor, SIMONOV, Yurii A., SCHMIDTMANN, Marc, MULLER, Achim, ANDRUH, Marius. The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4′-dimethyl-2,2′-bispyridil and 2,2′-bispyrimidine). In: Revista de Chimie, 2004, vol. 55, pp. 678-682. ISSN 0034-7752.

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Revista de Chimie

Volumul 55 / 2004 / ISSN 0034-7752

The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4′-dimethyl-2,2′-bispyridil and 2,2′-bispyrimidine)

Sinteza, caracterizarea structuralǎ şi spectralǎ a doi noi compuşi de tipul [Cu(sal)(AA)(ClO4)] (sal = anionul aldehidei salicilice, AA = 4,4′-dimetil-2,2′-bispiridil şi 2,2′-bispirimidinǎ)

Pag. 678-682

Madalan Augustin M.¹, Melnik E.², Kravtsov Victor², Simonov Yurii A.², Schmidtmann Marc³, Muller Achim³, Andruh Marius¹

¹ University of Bucharest,
² Institute of Applied Physics, Academy of Sciences of Moldova,
³ Bielefeld University

Disponibil în IBN: 18 iunie 2024

Rezumat

Two new mononuclear complexes belonging to the series [Cu(sal)(AA)(ClO ₄)] (sal = salicylaldehydate, AA = aromatic diamines) have been obtained and crystallographically characterized. In the two compounds, [Cu(sal)(Me₂-bipy)(ClO₄)] and [Cu(sal)(bipym)(ClO ₄)] (Me₂-bipy = 4,4′-dimethyl-2,2′-bipyridine; bipym = 2,2′-bipyrimidine), the copper(II) ions exhibit a square pyramidal geometry with the chelatic ligands forming the basal plane and the perclorate anion coordinated in the apical position. The spectral properties of the two compounds were investigated in UV, visible and IR domains.

Cuvinte-cheie
Copper(II) complexes, crystal structure, UV spectra, π-π stacking

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<dc:creator>Madalan, A.</dc:creator>
<dc:creator>Melnic, E.I.</dc:creator>
<dc:creator>Kravţov, V.H.</dc:creator>
<dc:creator>Simonov, I.A.</dc:creator>
<dc:creator>Schmidtmann, M.</dc:creator>
<dc:creator>Muller, A.</dc:creator>
<dc:creator>Andruh, M.</dc:creator>
<dc:date>2004-09-01</dc:date>
<dc:description xml:lang='en'><p>Two new mononuclear complexes belonging to the series [Cu(sal)(AA)(ClO&nbsp;<sub>4</sub>)] (sal = salicylaldehydate, AA = aromatic diamines) have been obtained and crystallographically characterized. In the two compounds, [Cu(sal)(Me<sub>2</sub>-bipy)(ClO<sub>4</sub>)] and [Cu(sal)(bipym)(ClO&nbsp;<sub>4</sub>)] (Me<sub>2</sub>-bipy = 4,4&prime;-dimethyl-2,2&prime;-bipyridine; bipym = 2,2&prime;-bipyrimidine), the copper(II) ions exhibit a square pyramidal geometry with the chelatic ligands forming the basal plane and the perclorate anion coordinated in the apical position. The spectral properties of the two compounds were investigated in UV, visible and IR domains.</p></dc:description>
<dc:source>Revista de Chimie  () 678-682</dc:source>
<dc:subject>Copper(II) complexes</dc:subject>
<dc:subject>crystal structure</dc:subject>
<dc:subject>UV spectra</dc:subject>
<dc:subject>π-π stacking</dc:subject>
<dc:title>The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4&prime;-dimethyl-2,2&prime;-bispyridil and 2,2&prime;-bispyrimidine)</dc:title>
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