Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
49 0 |
SM ISO690:2012 LAIHO, Reino, LISUNOV, Konstantin, LÄHDERANTA, Erkki, STAMOV, Vladimir, ZAKHVALINSKII, Vasilii. Variable-range hopping conductivity in La1-xCaxMnO3. In: Journal of Physics Condensed Matter, 2001, vol. 13, pp. 1233-1246. ISSN 0953-8984. DOI: https://doi.org/10.1088/0953-8984/13/6/304 |
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Journal of Physics Condensed Matter | ||||||
Volumul 13 / 2001 / ISSN 0953-8984 /ISSNe 1361-648X | ||||||
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DOI:https://doi.org/10.1088/0953-8984/13/6/304 | ||||||
Pag. 1233-1246 | ||||||
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In ceramic La1-3CaxMnO3 samples with 0 ≤ x ≤ 0.15 and the concentration of holes c = 0.18-0.22 between T = 77 and 340 K the resistivity, ρ, is shown to have an activated character both above and below the ferromagnetic Curie temperature, TC. The temperature dependence of the local activation energy, Eloc (T) = d 1n ρ(T)/d(kT)-1 gives evidence for a variable-range hopping conductivity over states of the Coulomb gap. The width of the gap Δ ≈ 0.24eV, the effective dielectric permeability κ ≈ 3.6 and the carrier localization radius ξ ≈ 5.1 angstrom in the paramagnetic phase are determined. The value of ξ suggests hopping of small lattice polarons at T > TC. With decreasing temperature two successive transitions, at temperatures T′C and T″C, associated with divergence of the correlation length, are observed in the vicinity of TC. They can be interpreted in terms of critical increase (as T approaches T′C from higher temperatures) and decrease (when T shifts from T″C towards lower temperatures) of the radius of magnetic polarons, generated by a small fraction of the lattice polarons as T → TC. The difference between TC and the temperature of the first divergence of ξ, T′C < TC, gives evidence of percolative character of the FM-PM transition. |
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Cuvinte-cheie Engineering controlled terms Activation energy, Carrier concentration, Crystal lattices, Electric conductivity of solids, Electron transitions, ferromagnetism, magnetization, Paramagnetism, Polarons, Thermal effects, X ray diffraction analysis Engineering uncontrolled terms Coulomb gap, dielectric permeability, Lanthanum calcium manganate, Lattice polarons, Magnetic polarons, Variable range hopping conductivity Engineering main heading Lanthanum compounds |
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