Variable-range hopping conductivity in La1-xCaxMnO3
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LAIHO, Reino, LISUNOV, Konstantin, LÄHDERANTA, Erkki, STAMOV, Vladimir, ZAKHVALINSKII, Vasilii. Variable-range hopping conductivity in La1-xCaxMnO3. In: Journal of Physics Condensed Matter, 2001, vol. 13, pp. 1233-1246. ISSN 0953-8984. DOI: https://doi.org/10.1088/0953-8984/13/6/304
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Journal of Physics Condensed Matter
Volumul 13 / 2001 / ISSN 0953-8984 /ISSNe 1361-648X

Variable-range hopping conductivity in La1-xCaxMnO3

DOI:https://doi.org/10.1088/0953-8984/13/6/304

Pag. 1233-1246

Laiho Reino1, Lisunov Konstantin2, Lähderanta Erkki1, Stamov Vladimir2, Zakhvalinskii Vasilii2
 
1 Wihuri Physical Laboratory, University of Turku,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 4 martie 2024


Rezumat

In ceramic La1-3CaxMnO3 samples with 0 ≤ x ≤ 0.15 and the concentration of holes c = 0.18-0.22 between T = 77 and 340 K the resistivity, ρ, is shown to have an activated character both above and below the ferromagnetic Curie temperature, TC. The temperature dependence of the local activation energy, Eloc (T) = d 1n ρ(T)/d(kT)-1 gives evidence for a variable-range hopping conductivity over states of the Coulomb gap. The width of the gap Δ ≈ 0.24eV, the effective dielectric permeability κ ≈ 3.6 and the carrier localization radius ξ ≈ 5.1 angstrom in the paramagnetic phase are determined. The value of ξ suggests hopping of small lattice polarons at T > TC. With decreasing temperature two successive transitions, at temperatures T′C and T″C, associated with divergence of the correlation length, are observed in the vicinity of TC. They can be interpreted in terms of critical increase (as T approaches T′C from higher temperatures) and decrease (when T shifts from T″C towards lower temperatures) of the radius of magnetic polarons, generated by a small fraction of the lattice polarons as T → TC. The difference between TC and the temperature of the first divergence of ξ, T′C < TC, gives evidence of percolative character of the FM-PM transition.

Cuvinte-cheie
Engineering controlled terms Activation energy, Carrier concentration, Crystal lattices, Electric conductivity of solids, Electron transitions, ferromagnetism, magnetization, Paramagnetism, Polarons, Thermal effects, X ray diffraction analysis Engineering uncontrolled terms Coulomb gap, dielectric permeability, Lanthanum calcium manganate, Lattice polarons, Magnetic polarons, Variable range hopping conductivity Engineering main heading Lanthanum compounds