The spontaneous emission probabilities for Ga-La-S:Pr3+ glass
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NISTREANU, Andrei, ENAKI, Nicolae, YOVU, M., KOROLI, Vlad, FURNISS, D., SEDDON, Angela B.. The spontaneous emission probabilities for Ga-La-S:Pr3+ glass. In: Journal of Optoelectronics and Advanced Materials, 2010, vol. 12, pp. 800-805. ISSN 1454-4164.
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Journal of Optoelectronics and Advanced Materials
Volumul 12 / 2010 / ISSN 1454-4164

The spontaneous emission probabilities for Ga-La-S:Pr3+ glass


Pag. 800-805

Nistreanu Andrei1, Enaki Nicolae1, Yovu M.1, Koroli Vlad2, Furniss D.3, Seddon Angela B.3
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 Institute of Chemistry of the Academy of Sciences of Moldova,
3 University of Nottingham
 
 
Disponibil în IBN: 27 februarie 2024


Rezumat

The absorption and emission spectra of chalcogenide glasses (Ga-La-S:O) doped with trivalent Praseodymium were experimentally investigated and theoretically discussed. The glasses show bright luminescence due to Pr 3+ ion emission. The effect of oxygen on the luminescence spectra is determined by decreasing of host glass self-absorption of the shortwavelength bands. In order to obtain the good agreement between the theoretical model and experimental results we apply the Judd-Ofelt theory for this glass matrix. Radiative transition rates are calculated and compared with measured experimental parameters. The radiative and non-radiative transition processes between the energy levels of the Pr3+ ions stimulated by optical and acoustical vibration modes are proposed in order to obtain the quantitative correlation between the proposed theoretical model and experimental results.

Cuvinte-cheie
Ga-La-S, Judd-Ofelt theory, optical absorption, Pr3, Rare-earth doped chalcogenide glasses

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<dc:creator>Nistreanu, A.I.</dc:creator>
<dc:creator>Enachi, N.A.</dc:creator>
<dc:creator>Iovu, M.S.</dc:creator>
<dc:creator>Coroli, V.I.</dc:creator>
<dc:creator>Furniss, D.</dc:creator>
<dc:creator>Seddon, A.</dc:creator>
<dc:date>2010-04-01</dc:date>
<dc:description xml:lang='en'><p>The absorption and emission spectra of chalcogenide glasses (Ga-La-S:O) doped with trivalent Praseodymium were experimentally investigated and theoretically discussed. The glasses show bright luminescence due to Pr&nbsp;<sup>3+</sup>&nbsp;ion emission. The effect of oxygen on the luminescence spectra is determined by decreasing of host glass self-absorption of the shortwavelength bands. In order to obtain the good agreement between the theoretical model and experimental results we apply the Judd-Ofelt theory for this glass matrix. Radiative transition rates are calculated and compared with measured experimental parameters. The radiative and non-radiative transition processes between the energy levels of the Pr<sup>3+</sup>&nbsp;ions stimulated by optical and acoustical vibration modes are proposed in order to obtain the quantitative correlation between the proposed theoretical model and experimental results.</p></dc:description>
<dc:source>Journal of Optoelectronics and Advanced Materials  () 800-805</dc:source>
<dc:subject>Ga-La-S</dc:subject>
<dc:subject>Judd-Ofelt theory</dc:subject>
<dc:subject>optical absorption</dc:subject>
<dc:subject>Pr3</dc:subject>
<dc:subject>Rare-earth doped chalcogenide glasses</dc:subject>
<dc:title>The spontaneous emission probabilities for Ga-La-S:Pr3+ glass</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
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