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SM ISO690:2012 NISTREANU, Andrei, ENAKI, Nicolae, YOVU, M., KOROLI, Vlad, FURNISS, D., SEDDON, Angela B.. The spontaneous emission probabilities for Ga-La-S:Pr3+ glass. In: Journal of Optoelectronics and Advanced Materials, 2010, vol. 12, pp. 800-805. ISSN 1454-4164. |
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Journal of Optoelectronics and Advanced Materials | ||||||
Volumul 12 / 2010 / ISSN 1454-4164 | ||||||
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Pag. 800-805 | ||||||
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The absorption and emission spectra of chalcogenide glasses (Ga-La-S:O) doped with trivalent Praseodymium were experimentally investigated and theoretically discussed. The glasses show bright luminescence due to Pr 3+ ion emission. The effect of oxygen on the luminescence spectra is determined by decreasing of host glass self-absorption of the shortwavelength bands. In order to obtain the good agreement between the theoretical model and experimental results we apply the Judd-Ofelt theory for this glass matrix. Radiative transition rates are calculated and compared with measured experimental parameters. The radiative and non-radiative transition processes between the energy levels of the Pr3+ ions stimulated by optical and acoustical vibration modes are proposed in order to obtain the quantitative correlation between the proposed theoretical model and experimental results. |
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Cuvinte-cheie Ga-La-S, Judd-Ofelt theory, optical absorption, Pr3, Rare-earth doped chalcogenide glasses |
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