Modification of the optical constants in amorphous Sb2Se 3:Sn thin films under the illumination and heat treatment
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HAREA, Diana, IOVU, Maria, IASENIUC, Oxana, KOLOMEYKO, Eduard, MESHALKIN, Alexei, YOVU, M.. Modification of the optical constants in amorphous Sb2Se 3:Sn thin films under the illumination and heat treatment. In: Journal of Optoelectronics and Advanced Materials, 2009, vol. 11, pp. 2039-2043. ISSN 1454-4164.
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Journal of Optoelectronics and Advanced Materials
Volumul 11 / 2009 / ISSN 1454-4164

Modification of the optical constants in amorphous Sb2Se 3:Sn thin films under the illumination and heat treatment


Pag. 2039-2043

Harea Diana, Iovu Maria, Iaseniuc Oxana, Kolomeyko Eduard, Meshalkin Alexei, Yovu M.
 
Institute of Applied Physics, Academy of Sciences of Moldova
 
Proiecte:
 
Disponibil în IBN: 26 februarie 2024


Rezumat

The optical properties of chalcogenide glasses present a great scientific interest for the establishment of the general legitimacy of interaction of the optical irradiation with the amorphous solids, as well as a practical interest. The effect of lightinduced photostructural transformations in amorphous chalcogenides films have been initiated many applications of amorphous material in photonics and optoelectronics, especially as inorganic photo-resists for sub-micron technology. The optical parameters of amorphous Sb2Se 3 and Sb2Se3:Snx (x=0.01, 0.5, 10 at. Sn %) prepared by vacuum evaporation on glass substrates was determined from transmission spectra. The band gap was found to be Eg=1.30 eV for amorphous Sb2Se3 and decrease with increasing of tin concentration up to Eg=1.0 eV for Sb2Se 3:Sn10.0. for determination of the refractive index the approximation method proposed by Valeev was used. The maximum modifications of the refractive index under the light irradiation δn (δn=0.20) occur for the composition Sb2Se3:Sn0.01. That allows us to conclude that doping of amorphous Sb2Se3 films with small concentrations of tin initiate the photostructural transformations under the light irradiation, and make these materials suitable for registration of optical and holographic information.

Cuvinte-cheie
Amorphous films, chalcogenide glasses, optical absorption, photoinduced phenomena, refractive index