Tetradecanuclear lanthanide-vanadium "nanochocolates": Catalytically-active cationic heteropolyoxovanadium clusters
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ŠIMUNEKOVÁ, Mária, PRODIUS, Denis, MERIAKRE, V., SCHWENDT, Peter, TURTA, Constantin, BETTINELLI, Marco, SPEGHINI, Adolfo, LAN, Yanhua, ANSON, Christopher E., POWELL, Annie Katherine. Tetradecanuclear lanthanide-vanadium "nanochocolates": Catalytically-active cationic heteropolyoxovanadium clusters. In: RSC Advances, 2013, vol. 3, pp. 6299-6304. ISSN 2046-2069. DOI: https://doi.org/10.1039/c3ra40385h
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RSC Advances
Volumul 3 / 2013 / ISSN 2046-2069

Tetradecanuclear lanthanide-vanadium "nanochocolates": Catalytically-active cationic heteropolyoxovanadium clusters

DOI:https://doi.org/10.1039/c3ra40385h

Pag. 6299-6304

Šimuneková Mária1, Prodius Denis23, Meriakre V.2, Schwendt Peter1, Turta Constantin3, Bettinelli Marco4, Speghini Adolfo4, Lan Yanhua2, Anson Christopher E.2, Powell Annie Katherine25
 
1 Comenius University,
2 Institute of Inorganic Chemistry, Karlsruhe Institute of Technology,
3 Institute of Chemistry of the Academy of Sciences of Moldova,
4 Università di Verona,
5 Karlsruhe Institute of Technology, Institute of Nanotechnology
 
 
Disponibil în IBN: 21 februarie 2024


Rezumat

The synthesis, structural characterization, magnetic and catalytic properties of a new class of lanthanide-containing cationic heteropolyoxovanadium clusters with a nanochocolate-like structure are reported. The title compounds were characterized by single-crystal and powder X-ray diffraction, IR and 51V-NMR spectroscopies and magnetic susceptibility measurements. 

Cuvinte-cheie
magnetic susceptibility, Nuclear Magnetic Resonance, Nuclear magnetic resonance spectroscopy, rare earth elements, X ray diffraction