Electronic structure of high-nuclearity mixed-valence clusters

Borras-Almenar Juan Jose; Clemente-Juan Juan; Coronado Eugenio; Georges Roland; Tsukerblat Boris S.

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539.3 (42)

Elasticitate. Deformare. Mecanica solidelor elastice (29)

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BORRAS-ALMENAR, Juan Jose, CLEMENTE-JUAN, Juan, CORONADO, Eugenio, GEORGES, Roland, TSUKERBLAT, Boris S.. Electronic structure of high-nuclearity mixed-valence clusters. In: Journal of Magnetism and Magnetic Materials, 1995, vol. 140-144, pp. 197-198. ISSN 0304-8853. DOI: https://doi.org/10.1016/0304-8853(94)01077-3

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Journal of Magnetism and Magnetic Materials

Volumul 140-144 / 1995 / ISSN 0304-8853

Electronic structure of high-nuclearity mixed-valence clusters

DOI:https://doi.org/10.1016/0304-8853(94)01077-3

CZU: 539.3

Pag. 197-198

Borras-Almenar Juan Jose¹², Clemente-Juan Juan¹, Coronado Eugenio¹, Georges Roland², Tsukerblat Boris S.¹³

¹ Universitat de València,
² Universitatea Bordeaux-1,
³ Institute of Chemistry of the Academy of Sciences of Moldova

Disponibil în IBN: 20 februarie 2024

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Rezumat

A general method is suggested for consideration of the electronic problem of high-nuclearity mixed-valence systems containing delocalized electronic pairs. A new approach based on the site symmetry concept with the electronic pairs is developed, and the magnetic properties of cluster metal oxides (heteropoly-blues) involving 12 and 18 metal sites are considered.

Cuvinte-cheie
Engineering controlled terms Antiferromagnetism, Electron transport properties, electronic structure, magnetic properties, Molybdenum compounds, Tungsten compounds Engineering uncontrolled terms Complex high nuclearity clusters, Electron delocalization, Electron pairs, Electron storage capacity, Heteropoly complexes, Interelectronic Coulomb repulsion, Keggin structure, Magnetic interaction, Mixed valence compounds, Polyoxometalate Engineering main heading Magnetic materials