Raman-active modes of porous gallium phosphide at high pressures and low temperatures
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URSACHI, Veaceslav, MANJON, Francisco Javier, SYASSEN, Karl, TIGINYANU, Ion, IRMER, Gert, MONECKE, Jochen. Raman-active modes of porous gallium phosphide at high pressures and low temperatures. In: Journal of Physics Condensed Matter, 2002, vol. 14, pp. 13879-13887. ISSN 0953-8984. DOI: https://doi.org/10.1088/0953-8984/14/50/313
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Journal of Physics Condensed Matter
Volumul 14 / 2002 / ISSN 0953-8984 /ISSNe 1361-648X

Raman-active modes of porous gallium phosphide at high pressures and low temperatures

DOI:https://doi.org/10.1088/0953-8984/14/50/313

Pag. 13879-13887

Ursachi Veaceslav12, Manjon Francisco Javier13, Syassen Karl1, Tiginyanu Ion24, Irmer Gert5, Monecke Jochen5
 
1 Max Planck Institute for Solid State Research,
2 Institute of Applied Physics, Academy of Sciences of Moldova,
3 Universitat Politècnica de València,
4 Technical University of Moldova,
5 Institut für Theoretische Physik, TU Bergakademie Freiberg
 
 
Disponibil în IBN: 13 februarie 2024


Rezumat

Porous gallium phosphide (GAP) with a honeycomb-like morphology and a skeleton relative volume concentration c = 0.7 was investigated by Raman spectroscopy under pressure up to 10 GPa at T = 5 K. The porous samples were prepared by electrochemical etching. The transverse optical (TO) and longitudinal optical (LO) mode frequencies were found to shift with pressure similarly to those of bulk GAP. As in bulk GaP, the TO feature of the porous GAP exhibits a pressure-induced narrowing which is interpreted in terms of a Fermi resonance. The scattering intensity observed on the low-frequency side of the LO mode is attributed to surface-related Fröhlich mode scattering. The latter results are interpreted on the basis of an effective medium expression for the dielectric function. The Raman spectra indicate that both the morphology and degree of porosity are unaffected by pressure in the range investigated.

Cuvinte-cheie
etching, High pressure effects, High temperature effects, morphology, porous materials, Raman spectroscopy, resonance, scattering