The hydrogen-bonded adduct 7,16-diazonia-18-crown-6-4-amino-benzensulfonate-water (1/2/2)

Fonari Marina; Simonov Yurii A.; Botoshansky Mark; Ganin Eduard; Yavolovskii Arkadii

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FONARI, Marina, SIMONOV, Yurii A., BOTOSHANSKY, Mark, GANIN, Eduard, YAVOLOVSKII, Arkadii. The hydrogen-bonded adduct 7,16-diazonia-18-crown-6-4-amino-benzensulfonate-water (1/2/2). In: Acta Crystallographica Section C: Crystal Structure Communications, 2003, vol. 59, pp. 88-90. ISSN 0108-2701. DOI: https://doi.org/10.1107/S010827010300129X

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Acta Crystallographica Section C: Crystal Structure Communications

Volumul 59 / 2003 / ISSN 0108-2701 /ISSNe 1600-5759

The hydrogen-bonded adduct 7,16-diazonia-18-crown-6-4-amino-benzensulfonate-water (1/2/2)

DOI:https://doi.org/10.1107/S010827010300129X

Pag. 88-90

Fonari Marina¹, Simonov Yurii A.¹, Botoshansky Mark², Ganin Eduard³, Yavolovskii Arkadii⁴

¹ Institute of Applied Physics, Academy of Sciences of Moldova,
² Technion-Israel Institute of Technology,
³ Odessa State Environmental University,
⁴ A.V. Bogatsky Physico-Chemical Institute of the NAS of Ukraine

Disponibil în IBN: 8 noiembrie 2023

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Rezumat

In the title hydrated adduct, 1,4,10,13-tetraoxa-7,16-diazonia-cyclooctadecane bis(4-aminobenzenesulfonate) dihydrate, C₁₂H₂₈N₂O₄²⁺ ·2C₆H₆NO₃S^- ·2H₂O, formed between 7,16-diaza-18-crown-6 and the dihydrate of 4-aminobenzenesulfonic acid, the macrocyclic cations lie across centres of inversion in the orthorhombic space group Pbca. The anions alone form zigzag chains, and the cations and anions together form sheets that are linked via water molecules and anions to form a three-dimensional grid.

Cuvinte-cheie
hydration, Hydrogen bonds, Molecules, Positive ions, Supramolecular chemistry