Optical constants of Cu2ZnGeS4 bulk crystals
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LEON, Maximo, LEVCENKO, Sergiu, SERNA, Rosalia, GURIEVA, Galina, NATEPROV, Alexander, MERINO, Jose Manuel, FRIEDRICH KERNAHAN, Eberhardt Josue, FILLAT, Úrsula, SCHORR, S., ARUSHANOV, Ernest. Optical constants of Cu2ZnGeS4 bulk crystals. In: Journal of Applied Physics, 2010, vol. 108, pp. 1-6. ISSN 0021-8979. DOI: https://doi.org/10.1063/1.3500439
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Journal of Applied Physics
Volumul 108 / 2010 / ISSN 0021-8979 /ISSNe 1089-7550

Optical constants of Cu2ZnGeS4 bulk crystals

DOI:https://doi.org/10.1063/1.3500439

Pag. 1-6

Leon Maximo1, Levcenko Sergiu2, Serna Rosalia3, Gurieva Galina2, Nateprov Alexander2, Merino Jose Manuel1, Friedrich Kernahan Eberhardt Josue1, Fillat Úrsula1, Schorr S.4, Arushanov Ernest12
 
1 Universidad Autónoma de Madrid,
2 Institute of Applied Physics, Academy of Sciences of Moldova,
3 Instituto de Optica, IO, CSIC,
4 Free University of Berlin, Germany
 
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Disponibil în IBN: 6 noiembrie 2023


Rezumat

The dielectric functions of Cu2 ZnGeS4 bulk crystals grown by the Bridgman method were measured over the energy range 1.4 to 4.7 eV at room temperature using variable angle spectroscopic ellipsometry. The observed structures in the dielectric functions were adjusted using the Adachi's model and attributed to interband transitions E0, E1A, and E1B at :(000), N (A):2π /a (0.5 0.5 0.5), and T (Z):2π /a (0 0 0.5) points of the first Brillouin zone, respectively. The model parameters (threshold energy, strength, and broadening) have been determined using the simulated annealing algorithm. The decrease in the first gap, E0, has been attributed to a higher Ge-S hybridization. The spectral dependence of the complex refractive index, the absorption coefficient, and the normal-incidence reflectivity were also derived. 

Cuvinte-cheie
Engineering controlled terms Computer simulation, Crystal growth from melt, Crystals, Germanium, Optical constants, refractive index, Spectroscopic ellipsometry Engineering uncontrolled terms Absorption coefficients, Bridgman methods, Bulk crystals, Complex refractive index, Dielectric functions, Energy ranges, First Brillouin zone, Inter-band transition, Model parameters, Room temperature, Simulated annealing algorithms, Spectral dependences, Threshold energy, Variable angle spectroscopic ellipsometry Engineering main heading Simulated annealing