Optical characterization of CuIn 3Se 5, CuGa 3Se 5 and CuGa 5Se 8 crystals by spectroscopic ellipsometry
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LEON, Maximo, SERNA, Rosalia, LEVCENKO, Sergiu, NATEPROV, Alexander, NIKORICH, Andrey V., MERINO, Jose Manuel, ARUSHANOV, Ernest. Optical characterization of CuIn 3Se 5, CuGa 3Se 5 and CuGa 5Se 8 crystals by spectroscopic ellipsometry. In: Physica Status Solidi (A) Applications and Materials Science, 2006, vol. 203, pp. 2913-2918. ISSN 1862-6300. DOI: https://doi.org/10.1002/pssa.200669504
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Physica Status Solidi (A) Applications and Materials Science
Volumul 203 / 2006 / ISSN 1862-6300

Optical characterization of CuIn 3Se 5, CuGa 3Se 5 and CuGa 5Se 8 crystals by spectroscopic ellipsometry

DOI:https://doi.org/10.1002/pssa.200669504

Pag. 2913-2918

Leon Maximo1, Serna Rosalia2, Levcenko Sergiu3, Nateprov Alexander3, Nikorich Andrey V.3, Merino Jose Manuel1, Arushanov Ernest13
 
1 Universidad Autónoma de Madrid,
2 Instituto de Optica, IO, CSIC,
3 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 4 octombrie 2023


Rezumat

The ellipsometric spectra of CuIn 3Se 5, CuGa 3Se 5 and CuGa 5Se 8 ordered vacancy compounds (OVC) have been studied in the spectral range from 0.8 to 4.4 eV. The structures observed in the measured spectra were analyzed by fitting the second derivative of the experimental spectrum to analytical line shapes. The energies corresponding to different electronic transitions were determined. The lowest direct gap (E 0) is characterized by 3-dimensional critical points, while higher energy structures are characterized by 2D critical points. Optical constants related to dielectric function, such as the complex refractive index n*(ω), extinction coefficient k(ω), absorption coefficient 0(ω), and normal-incidence reflectivity R(ω), of studied OVC were determined. 

Cuvinte-cheie
Copper compounds, Electron transitions, Ellipsometry, Gallium compounds, optical properties, Spectroscopic analysis