Calculation of the possibility of formation of a cyclic metallolactone anionic complex in the methyloxirane-potassium tetracarbonylcobaltate system

Boyarskii Vadim; Boyarskaya Irina; Duka Gh.

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BOYARSKII, Vadim, BOYARSKAYA, Irina, DUKA, Gh.. Calculation of the possibility of formation of a cyclic metallolactone anionic complex in the methyloxirane-potassium tetracarbonylcobaltate system. In: Russian Journal of General Chemistry, 2008, vol. 78, pp. 1380-1381. ISSN 1070-3632. DOI: https://doi.org/10.1134/S1070363208070153

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Russian Journal of General Chemistry

Volumul 78 / 2008 / ISSN 1070-3632 /ISSNe 1608-3350

Calculation of the possibility of formation of a cyclic metallolactone anionic complex in the methyloxirane-potassium tetracarbonylcobaltate system

DOI:https://doi.org/10.1134/S1070363208070153

Pag. 1380-1381

Boyarskii Vadim¹, Boyarskaya Irina¹, Duka Gh.²

¹ Saint Petersburg State University,
² Academy of Sciences of Moldova

Disponibil în IBN: 21 septembrie 2023

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The reaction of the tetracarbonylcobaltate anion with methyloxirane was studied by quantumchemical methods to show that a metallocyclic complex is energetically preferred over an alkylcobaltcarbonyl one

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