Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
139 0 |
SM ISO690:2012 ZIVKOVIC, Ljiljana S., LAIR, Virginie, LUPAN, Oleg, RINGUEDE, Armelle. Electrochemical synthesis and properties of ceria films grown on stainless steel. In: Russian Journal of Physical Chemistry A, 2011, vol. 85, pp. 2358-2362. ISSN 0036-0244. DOI: https://doi.org/10.1134/S003602441113036X |
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Russian Journal of Physical Chemistry A | ||||||
Volumul 85 / 2011 / ISSN 0036-0244 /ISSNe 1531-863X | ||||||
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DOI:https://doi.org/10.1134/S003602441113036X | ||||||
Pag. 2358-2362 | ||||||
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Electrochemical synthesis of ceria films was performed on a stainless steel substrate in view of Solid Oxide Fuel Cells (SOFC) applications. Films were obtained from aqueous nitrate solutions via cathodic deposition method at room temperature. A constant potential value of –0.8 V/(SCE) was applied to reduce the molecular oxygen as hydroxide precursor, leading to a formation of adherent, homogeneous and covering films in 20 min deposition time. Structure, morphology and composition of as-grown coatings were studied by X-ray diffraction, Raman and energy-dispersive X-ray spectroscopy, as well as scanning electron microscopy. Cubic fluorite-type nanostructured ceria of leaf-like particles was synthesized. Thermal annealing (600°C, 1 h) was found to enhance ceria crystallinity. |
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Cuvinte-cheie Ceria films, Crystallinity, electrochemistry, synthesis |
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