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 SM ISO690:2012NOVITSKY, Ghenadie, BORTA, A., GANZHU, D., SHOVA, Sergiu, FILIPPOVA, Irina, SIMONOV, Yurii A.. Chemical transformations of lanthanide nitrate complexes: Synthesis and X-ray diffraction analysis. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2009, vol. 35, pp. 381-388. ISSN -. DOI: https://doi.org/10.1134/S107032840905011X |
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  Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
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| Volumul 35 / 2009 / ISSN - /ISSNe 1070-3284 | |||||||
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| DOI:https://doi.org/10.1134/S107032840905011X | |||||||
| Pag. 381-388 | |||||||
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The complexes [Dy(NO3)3(Bipy)2], (HBipy)[Gd(NO3)4(Bipy)], and [FeIII(Me 2Bipy)3][La(NO3)5(H 2O)]NO3 and the precursor of the latter, [Fe IIPc2(Me2Bipy)](CHCl3) • 1.5H2O (where Bipy is the 2,2?-bipyridyl, Me2Bipy is the 4,4?-dimethyl-2,2?-bipyridyl, and Pc- is the pyridine-2-carboxylate anion), were obtained and characterized by X-ray diffraction analysis. Depending on the conditions of the synthesis and the reagents, the number of coordinated nitrate groups in the lanthanide complex increases from three to five: [Dy(NO3)3(Bipy)2], [Gd(NO3) 4(Bipy)]-, and [La(NO3)5(H 2O)]2-. |
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| Cuvinte-cheie Engineering controlled terms Carboxylation, complexation, Coordination reactions, Diffraction, Gadolinium, lanthanum, Synthesis (chemical), X ray diffraction Engineering uncontrolled terms Bipyridyl, Carboxylate anions, Chemical transformations, lanthanide, lanthanide complex, Nitrate complexes, Nitrate groups, Pyridine-2 Engineering main heading X ray diffraction analysis |
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