Supramolecular architecture of the [M(1-MeIm)2(H 2O)4]2+ (M = Ni, Co) complexes with the terephthalate anion

Malaestean Yurii; Filippova Irina; Ellern Arkady M.; Simonov Yurii A.; Baca Svetlana

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MALAESTEAN, Yurii, FILIPPOVA, Irina, ELLERN, Arkady M., SIMONOV, Yurii A., BACA, Svetlana. Supramolecular architecture of the [M(1-MeIm)2(H 2O)4]2+ (M = Ni, Co) complexes with the terephthalate anion. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2008, vol. 34, pp. 334-338. ISSN -. DOI: https://doi.org/10.1134/S1070328408050047

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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

Volumul 34 / 2008 / ISSN - /ISSNe 1070-3284

Supramolecular architecture of the [M(1-MeIm)₂(H ₂O)₄]²⁺ (M = Ni, Co) complexes with the terephthalate anion

DOI:https://doi.org/10.1134/S1070328408050047

Pag. 334-338

Malaestean Yurii¹, Filippova Irina², Ellern Arkady M.³, Simonov Yurii A.², Baca Svetlana¹

¹ Institute of Chemistry of the Academy of Sciences of Moldova,
² Institute of Applied Physics, Academy of Sciences of Moldova,
³ Iowa State University, Ames

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Menționat în lucrare: MTFP-04-03 Complecși ai metalelor de tip 3d cu nuclearitate înaltă în baza carboxilaților: design, sinteză și proprietăți

Disponibil în IBN: 14 septembrie 2023

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The [M(1-MeIm)₂(H₂O)₄](Tpht) • 4H₂O complexes (where M = Ni, Co; 1-MeIm is 1-methylimidazole; H ₂Tpht is terephthalic acid) are synthesized and characterized by X-ray diffraction analysis. The ionic structure is built of the [M(1-MeIm) ₂(H₂O)₄]²⁺ cations and (Tpht) ^2- anions. The metal ions have a distorted octahedral coordination. The cations and anions are united by hydrogen bonding system.

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Engineering controlled terms, Microfluidics, Engineering uncontrolled terms, Supramolecular architectures, Engineering main heading