Influence of transitions among degenerated states of atoms and molecules on some physico-chemical quantities of liquids: Vaporization entropies of liquid 3d-metals
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GORBACHEV, Mikhail. Influence of transitions among degenerated states of atoms and molecules on some physico-chemical quantities of liquids: Vaporization entropies of liquid 3d-metals. In: Physics and Chemistry of Liquids, 2000, vol. 38, pp. 17-23. ISSN 0031-9104. DOI: https://doi.org/10.1080/00319100008045293
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Physics and Chemistry of Liquids
Volumul 38 / 2000 / ISSN 0031-9104 /ISSNe 1029-0451

Influence of transitions among degenerated states of atoms and molecules on some physico-chemical quantities of liquids: Vaporization entropies of liquid 3d-metals

DOI:https://doi.org/10.1080/00319100008045293

Pag. 17-23

Gorbachev Mikhail
 
Institute of Chemistry of the Academy of Sciences of Moldova
 
 
Disponibil în IBN: 13 septembrie 2023


Rezumat

The equation, describing the vaporization entropies of liquid 3d-metals and taking into account the electronic distribution of 3d-metals' atoms, is received by the use of the assumption about the general character of the relationship, which characterizes the influence of transitions among degenerated states of atoms and molecules on physico-chemical quantities of liquids. It is shown that the vaporization entropies of these metals can be calculated adequately by means of this equation.The equation, describing the vaporization entropies of liquid 3d-metals and taking into account the electronic distribution of 3d-metals' atoms, is received by the use of the assumption about the general character of the relationship, which characterizes the influence of transitions among degenerated states of atoms and molecules on physico-chemical quantities of liquids. It is shown that the vaporization entropies of these metals can be calculated adequately by means of this equation.

Cuvinte-cheie
Degenerated states, Electronic distribution, Liquid 3d-metals, Vaporization entropies