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 SM ISO690:2012GORBACHEV, Mikhail. Semi-empirical relation between freezing point and critical point properties of a wide variety of molecular liquids. In: Physics and Chemistry of Liquids, 2009, vol. 47, pp. 188-193. ISSN 0031-9104. DOI: https://doi.org/10.1080/00319100701810222 |
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  Physics and Chemistry of Liquids |
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| Volumul 47 / 2009 / ISSN 0031-9104 /ISSNe 1029-0451 | ||||||
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| DOI:https://doi.org/10.1080/00319100701810222 | ||||||
| Pag. 188-193 | ||||||
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Based on experimental data for some 28 freezing liquids, we define a semi-empirical relation connecting surface tension and molar volume with the molar critical volume. It is shown that the semi-empirical equation deduced by means of this relation allows one to calculate the given critical property for various molecular liquids with high accuracy. |
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| Cuvinte-cheie energy balance, Freezing liquids, Molar critical volume |
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