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 SM ISO690:2012MADALAN, Augustin M., KRAVTSOV, Victor, SIMONOV, Yurii A., ANDRUH, Marius. [Cu(2,2'-bipy)(NCS)2], the missing term in the isostructural [Cu(AA)(NCS)2] series (AA = aromatic diamines). In: Revue Roumaine de Chimie, 2002, vol. 47, pp. 917-921. ISSN 0035-3930. |
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  Revue Roumaine de Chimie |
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| Volumul 47 / 2002 / ISSN 0035-3930 | ||||||
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| Pag. 917-921 | ||||||
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The crystal structure of [Cu(2,2'-bipy)(NCS)2] 1 has been solved. It crystallizes in the monoclinic system, a = 8.093(2) Å, b = 15.564(3) Å, c - 10.533(2) Å, β= 95.20(3) space group C2/c. The structure consists of infinite linear chains resulting through the connection of the copper(II) ions by double NCS bridges. The stereochemistry of the copper(II) ions is distorted octahedral. The metal-donor atoms distances are: Cu - N(bipy) = 1.999(10) Å; Cu - N(NCS) = 1.942(18) Å; Cu - S(1) = 3.222 Å. The distance between the copper atoms within a chain is 6.102 Å. |
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| Cuvinte-cheie Engineering controlled terms Acetylation, aromatic compounds, atoms, bonding, data acquisition, molecular structure, nitrogen compounds, Sulfur Engineering uncontrolled terms Aromatic diamines, Isothiocyanato ligands, Supramolecular level, Thiocyanate bridging Engineering main heading Crystal structure |
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