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 SM ISO690:2012TURTA, Constantin, SPATARU, Tudor, VREZHMASHU, V.. The nature of the chemical bond in trinuclear oxo carboxylates containing {FeIII2MIIO} cores vs. their spectral properties. In: Revue Roumaine de Chimie, 2001, vol. 46, pp. 861-871. ISSN 0035-3930. |
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  Revue Roumaine de Chimie |
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| Volumul 46 / 2001 / ISSN 0035-3930 | ||||||
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Quantum chemical analysis of the electronic structure and some spectral characteristics for iron mixed metal trinuclear oxo carboxylates [FeIII2MIIO(O2CCR)6L 3], where M=Mn, Fe, Co, and Ni; L=3-Cl-Py, Py or H2O and R=CH3 or CF3 were performed. The obtained values are presented in comparison with those for the [Fe3O(OAc)6(H2O)3]+ cation, and are in good agreement with experimental Mossbauer spectra. The analysis of the electronic structure permits to put into evidence general features observed also in IR and electronic spectra. |
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Dublin Core Export
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<oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'>
<dc:creator>Turtă, C.I.</dc:creator>
<dc:creator>Spataru, T.A.</dc:creator>
<dc:creator>Vrăjmasu, V.V.</dc:creator>
<dc:date>2001-08-08</dc:date>
<dc:description xml:lang='en'><p>Quantum chemical analysis of the electronic structure and some spectral characteristics for iron mixed metal trinuclear oxo carboxylates [Fe<sup>III</sup><sub>2</sub>M<sup>II</sup>O(O<sub>2</sub>CCR)<sub>6</sub>L <sub>3</sub>], where M=Mn, Fe, Co, and Ni; L=3-Cl-Py, Py or H<sub>2</sub>O and R=CH<sub>3</sub> or CF<sub>3</sub> were performed. The obtained values are presented in comparison with those for the [Fe<sub>3</sub>O(OAc)<sub>6</sub>(H<sub>2</sub>O)<sub>3</sub>]<sup>+</sup> cation, and are in good agreement with experimental Mossbauer spectra. The analysis of the electronic structure permits to put into evidence general features observed also in IR and electronic spectra.</p></dc:description>
<dc:source>Revue Roumaine de Chimie () 861-871</dc:source>
<dc:title>The nature of the chemical bond in trinuclear oxo carboxylates containing {FeIII2MIIO} cores vs. their spectral properties</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
</oai_dc:dc>|
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