| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 101 0 |
 SM ISO690:2012CONSTANTINESCU, Elena, STORCH, Herbert, TURTA, Constantin, MERIAKRE, V.. Cyclic voltammetric and spectral study of the trinuclear complex [Fe2 IIIFeIIO(CF3COO) 6(OPPh3)3]. In: Revue Roumaine de Chimie, 1998, vol. 43, pp. 799-803. ISSN 0035-3930. |
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  Revue Roumaine de Chimie |
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| Volumul 43 / 1998 / ISSN 0035-3930 | ||||||
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| Pag. 799-803 | ||||||
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The heterovalent trinuclear oxo bridged compound [Fe2 III FeIIO(CF3COO)6(OPPh3)3] was characterised by IR and Moessbauer spectral analysis. Cyclic voltammetric study at stationary platinum electrode was performed in dimethylsulfoxide with 0.1 M tetrabutylammoniumperchlorate as supporting electrolyte. The voltammograms recorded in the potential range +0.2 to -1.6 V exhibit four reduction waves (only the first one is reversible). The electrochemical standard rate constant of the reversible charge transfer step was established. |
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