{Fe6O2}-based assembly of a tetradecanuclear iron nanocluster

Baca Svetlana; Speldrich Manfred; Ellern Arkady M.; Kogerler Paul

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2023-09-13 16:05

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BACA, Svetlana, SPELDRICH, Manfred, ELLERN, Arkady M., KOGERLER, Paul. {Fe6O2}-based assembly of a tetradecanuclear iron nanocluster. In: Materials, 2010, vol. 4, p. 0. ISSN 1996-1944. DOI: https://doi.org/10.3390/ma4010300

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Materials

Volumul 4 / 2010 / ISSN 1996-1944

{Fe₆O₂}-based assembly of a tetradecanuclear iron nanocluster

DOI:https://doi.org/10.3390/ma4010300

Pag. 0-0

Baca Svetlana¹², Speldrich Manfred¹, Ellern Arkady M.³, Kogerler Paul¹³⁴

¹ Institute of Inorganic Chemistry RWTH Aachen University,
² Institute of Chemistry of the Academy of Sciences of Moldova,
³ Iowa State University, Ames,
⁴ Research Center Jülich GmbH, Garching

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Menționat în lucrare: 09.820.05.10GF Materiale magnetice în baza polimerilor coordinativi

Disponibil în IBN: 29 august 2023

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The tetradecanuclear Fe^III pivalate nanocluster [Fe₁₄O₁₀(OH)₄(Piv)₁₈], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core

Cuvinte-cheie
Iron(III) carboxylates, magnetic properties, Solvothermal synthesis, X-Ray structure