Obtaining and characterizing modified tannins by physical-chemical methods
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GONTA, Alexandru, LUPASCU, Tudor, TIMBALIUC, Nina, MEGHEA, Aurelia. Obtaining and characterizing modified tannins by physical-chemical methods. In: Central European Journal of Chemistry, 2014, vol. 12, pp. 757- 762. ISSN 1895-1066. DOI: https://doi.org/10.2478/s11532-014-0505-7
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Central European Journal of Chemistry
Volumul 12 / 2014 / ISSN 1895-1066

Obtaining and characterizing modified tannins by physical-chemical methods

DOI:https://doi.org/10.2478/s11532-014-0505-7
CZU: 543.5:547.98

Pag. 757- 762

Gonta Alexandru1, Lupascu Tudor1, Timbaliuc Nina1, Meghea Aurelia2
 
1 Institute of Chemistry of the Academy of Sciences of Moldova,
2 University Politehnica of Bucharest
 
 
Disponibil în IBN: 17 august 2023


Rezumat

After oxidation of tannins (Tannins 1-3) extracted from grape seeds, Tanoxil compounds with increased solubility and enhanced antioxidant activities were synthesized. In this research, ABTS assay and a chemiluminescence method were used for antioxidant measurement of hydrophilic compounds (Tanoxils 1-3). It was observed that the antioxidant activity (AA, %) is very similar for the three samples, while at the same time AA is quite high (93.16%-96.48%). The percentage of inhibition by ABTS is higher for Tanoxil 2 (96.4%) as compared to Tannin 2 compound (14.34%). Moreover, the total content (TCF) of carboxyl and phenolic groups was investigated. TCF values, determined for Tanoxil products, revealed a double (Tanoxil 1) or triple (Tanoxil 2) increase as compared to the value of the TCF of Tannin 1. Tanoxil products represent an interest for future research as they have a high AA (96.4%) and the content of acidic groups is significant (TCF, 0.191 meq g-1). [Figure not available: see fulltext.]

Cuvinte-cheie
antioxidant, chemiluminescence, polyphenols, tannins