Benzoxazole-based heterometallic dodecanuclear complex [Dy III 4CuII 8] with single-molecule- magnet behavior
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IASCO, Olga, NOVITSKY, Ghenadie, JEANNEAU, Erwann, WERNSDORFER, Wolfgang, LUNEAU, Dominique. Benzoxazole-based heterometallic dodecanuclear complex [Dy III 4CuII 8] with single-molecule- magnet behavior. In: Inorganic Chemistry, 2011, vol. 50, pp. 7373- 7375. ISSN 0020-1669. DOI: https://doi.org/10.1021/ic201070n
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Inorganic Chemistry
Volumul 50 / 2011 / ISSN 0020-1669

Benzoxazole-based heterometallic dodecanuclear complex [Dy III 4CuII 8] with single-molecule- magnet behavior

DOI:https://doi.org/10.1021/ic201070n

Pag. 7373- 7375

Iasco Olga1, Novitsky Ghenadie12, Jeanneau Erwann1, Wernsdorfer Wolfgang3, Luneau Dominique1
 
1 Universitatea Claude Bernard Lyon 1,
2 Institute of Chemistry of the Academy of Sciences of Moldova,
3 Institut Néel CNRS/UGA UPR2940
 
 
Disponibil în IBN: 24 iulie 2023


Rezumat

hree Cu-Ln (Ln = Dy, Gd, Y) dodecanuclear clusters assembled by a novel ligand of the benzoxazole type are reported. The dysprosium cluster exhibits a frequency dependence of the alternating-current susceptibility and hysteresis loop at low temperature, indicating single-molecule-magnet behavior.