Phosphorotropic rearrangement in synthesis of asymmetrically-substituted calix[4]arenes

Markovsky Leonid; Visotsky Miroslav; Pirozhenko Vladimir; Kalchenko Vitaly; Lipkowski Janusz; Simonov Yurii A.

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120

SM ISO690:2012

MARKOVSKY, Leonid, VISOTSKY, Miroslav, PIROZHENKO, Vladimir, KALCHENKO, Vitaly, LIPKOWSKI, Janusz, SIMONOV, Yurii A.. Phosphorotropic rearrangement in synthesis of asymmetrically-substituted calix[4]arenes. In: Chemical Communications, 2013, vol. 49, pp. 69-71. ISSN 1359-7345. DOI: https://doi.org/10.1039/cc9960000069

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Chemical Communications

Volumul 49 / 2013 / ISSN 1359-7345 /ISSNe 1364-548X

Phosphorotropic rearrangement in synthesis of asymmetrically-substituted calix[4]arenes

DOI:https://doi.org/10.1039/cc9960000069

Pag. 69-71

Markovsky Leonid¹, Visotsky Miroslav¹, Pirozhenko Vladimir¹, Kalchenko Vitaly¹, Lipkowski Janusz², Simonov Yurii A.³

¹ Institute of Organic Chemistry NAS of Ukraine,
² Institute of Physical Chemistry of the Polish Academy of Sciences, Polonia,
³ Institute of Applied Physics, Academy of Sciences of Moldova

Disponibil în IBN: 17 iulie 2023

Rezumat

Monosodium derivatives of 1,3-bis(diethoxyphosphoryl)-calix[4]arenes undergo O,O-phosphorotropic rearrangement into corresponding 1,2-bis(diethoxyphosphoryl)calix[4]arenes which are useful reagents in the synthesis of asymmetrically substituted calix[4]arenes with AABH-type substitution of the lower rim.