| Conţinutul numărului revistei |
| Articolul precedent |
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 SM ISO690:2012CAIRNS, Amy, PERMAN, Jason A., WOJTAS, Łukasz, KRAVTSOV, Victor, ALKORDI, Mohamed H., EDDAOUDI, Mohamed, ZAWOROTKO, Michael. Supermolecular Building Blocks (SBBs) and crystal design: 12-Connected open frameworks based on a molecular cubohemioctahedron. In: Journal of the American Chemical Society, 2008, vol. 130, pp. 1560-1561. ISSN 0002-7863. DOI: https://doi.org/10.1021/ja078060t |
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| Journal of the American Chemical Society | ||||||
| Volumul 130 / 2008 / ISSN 0002-7863 /ISSNe 1520-5126 | ||||||
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| DOI:https://doi.org/10.1021/ja078060t | ||||||
| Pag. 1560-1561 | ||||||
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The cubohemioctahedral supermolecular building blocks, SBBs, of formula [M6(bdc)12]12- (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid tetracarboxylato ligands in such a manner that 12-connected fcu nets with nanoscale features are generated. 3,5-H4ATC, L1, facilitates a structure with Ni that exhibits cavities with >2 nm maximum dimensions, whereas H4BIPA-TC, L2, forms a net with Co or Ni that exhibits cavities with >3 nm maximum dimensions. |
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| Cuvinte-cheie EMTREE drug terms 1, 3 benzenedicarboxylate, cobalt, dicarboxylic acid derivative, nickel, unclassified drug EMTREE medical terms adsorption, article, chemical structure, cross linking, Crystal, crystal structure, geometry, reaction analysis, structure analysis, supermolecular building block, synthesis |
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