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| Articolul urmator |
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 160 2 |
| Ultima descărcare din IBN: 2024-04-07 12:01 |
| Căutarea după subiecte similare conform CZU |
| 544.122.2 (1) |
| Structura chimică a materiei (98) |
 SM ISO690:2012MIKURIYA, Masahiro, KAWAUCHI, Shun, MITSUHASHI, Ryoji, TSUBOI, Motohiro, HANDA, Makoto. Geometrical isomerism in Ru2Au heterometal assembly: cis-linking of tetracyanidoaurate to tetrakis(μ-butanoato)diruthenium. In: Chemistry Journal of Moldova, 2023, nr. 1(18), pp. 77-85. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2023.1059 |
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  Chemistry Journal of Moldova |
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| Numărul 1(18) / 2023 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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| DOI:https://doi.org/10.19261/cjm.2023.1059 | ||||||
| CZU: 544.122.2 | ||||||
| Pag. 77-85 | ||||||
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A heterometal assembled complex of tetrakis(μ-butanoato)diruthenium(II,III) and tetracyanidoaurate(III) [RuIIRuIII(n-C3H7COO)4AuIII(CN)4]n was synthesized and characterized by the elemental analysis and infrared spectroscopy. The single-crystal X-ray structure analysis revealed that the complex consists of zigzag chain molecules of alternating arrangement of the Ru2(n-C3H7COO)4+ and Au(CN)4– units with cis-bridging mode of the Au(CN)4– units. The temperature dependence of the magnetic susceptibility data (4.5—300 K) showed that the magnetic interaction between the dinuclear RuIIRuIII units (S= 3/2) is negligibly small with a zero-field splitting parameter D value of 60 cm-1. |
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