Synthesis and physical characteristics of narrow bandgap chalcogenide SnZrSe 3
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KONDROTAS , Rokas, JUSKENAS, Remigijus L., KROTKUS, Arunas, PAKSTAS, Vidas, SUCHODOLSKIS, Arturas, MEKYS, Algirdas, FRANCKEVICIUS, Marius, TALAIKIS, Martynas, MUSKA, Katri, LI, Xiaofeng, KAUK-KUUSIK, Marit, KRAVTSOV, Victor. Synthesis and physical characteristics of narrow bandgap chalcogenide SnZrSe 3. In: Open Research Europe, 2023, vol. 2, p. 0. ISSN 2732-5121. DOI: https://doi.org/10.12688/openreseurope.15168.2
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Open Research Europe
Volumul 2 / 2023 / ISSN 2732-5121

Synthesis and physical characteristics of narrow bandgap chalcogenide SnZrSe 3

DOI:https://doi.org/10.12688/openreseurope.15168.2

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Kondrotas Rokas1, Juskenas Remigijus L.1, Krotkus Arunas1, Pakstas Vidas1, Suchodolskis Arturas1, Mekys Algirdas2, Franckevicius Marius1, Talaikis Martynas1, Muska Katri3, Li Xiaofeng3, Kauk-Kuusik Marit3, Kravtsov Victor4
 
1 Center for Physical Sciences and Technology,
2 Vilnius University,
3 Tallinn University of Technology,
4 Institute of Applied Physics, MSU
 
 
Disponibil în IBN: 22 iunie 2023


Rezumat

Background: The development of organic/inorganic metal halide perovskites has seen unprecedent growth since their first recognition for applications in optoelectronic devices. However, their thermodynamic stability and toxicity remains a challenge considering wide-scale deployment in the future. This spurred an interest in search of perovskite-inspired materials which are expected to retain the advantageous material characteristics of halide perovskites, but with high thermodynamic stability and composed of earth-abundant and low toxicity elements. ABX 3 chalcogenides (A, B=metals, X=Se, S) have been identified as potential class of materials meeting the aforementioned criteria. Methods: In this work, we focus on studying tin zirconium selenide (SnZrSe 3) relevant physical properties with an aim to evaluate its prospects for application in optoelectronics. SnZrSe 3 powder and monocrystals were synthesized via solid state reaction in 600 – 800 °C temperature range. Crystalline structure was determined using single crystal and powder X-ray diffraction methods. The bandgap was estimated from diffused reflectance measurements on powder samples and electrical properties of crystals were analysed from temperature dependent I-V measurements. Results: We found that SnZrSe 3 crystals have a needle-like structure (space group – Pnma) with following unit cell parameters: a=9.5862(4) Å, b=3.84427(10) Å, c=14.3959(5) Å. The origin of the low symmetry crystalline structure was associated with stereochemical active electron lone pair of Sn cation. Estimated bandgap was around 1.15 eV which was higher than measured previously and predicted theoretically. Additionally, it was found that resistivity and conductivity type depended on the compound chemical composition. Conclusions: Absorption edge in the infrared region and bipolar dopability makes SnZrSe 3 an interesting material candidate for application in earth-abundant and non-toxic single/multi-junction solar cells or other infrared based optoelectronic devices. 

Cuvinte-cheie
ABX3 chalcogenides, bandgap, crystal structure, optoelectronic properties