Geometric frustration in the cubic spinels MAl2O4 (M=Co, Fe, and Mn)
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TRISTAN, Neumann, HEMBERGER, Joachim, KRIMMEL, Alexander, KRUG VON NIDDA, Hans Albrecht, TSURKAN, Vladimir, LOIDL, Alois. Geometric frustration in the cubic spinels MAl2O4 (M=Co, Fe, and Mn). In: Physical Review B - Condensed Matter and Materials Physics, 2005, vol. 72, p. 0. ISSN 1098-0121. DOI: https://doi.org/10.1103/PhysRevB.72.174404
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Physical Review B - Condensed Matter and Materials Physics
Volumul 72 / 2005 / ISSN 1098-0121 /ISSNe 1550-235X

Geometric frustration in the cubic spinels MAl2O4 (M=Co, Fe, and Mn)

DOI:https://doi.org/10.1103/PhysRevB.72.174404

Pag. 0-0

Tristan Neumann1, Hemberger Joachim1, Krimmel Alexander1, Krug Von Nidda Hans Albrecht1, Tsurkan Vladimir12, Loidl Alois1
 
1 Institut für Physik, Universität Augsburg,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 21 iunie 2023


Rezumat

X-ray diffraction, magnetic susceptibility, electron-spin resonance, and heat-capacity investigations were performed on MAl2O4 compounds with M=Co, Fe, Mn, and Zn. All compounds crystallize in cubic spinel structure AB2O4 with minor inversion between A and B sites. CoAl2O4 and FeAl2O4 reveal spin-glass-like ground states with freezing temperatures well below the Curie-Weiss temperatures indicating strong geometric frustration. Below the freezing temperatures, the heat capacities show a T2 temperature dependence for T→0K as has recently been observed in some related geometrically frustrated magnets, in contrast to the linear dependence expected for common spin glasses. The heat capacity of FeAl2O4 exhibits an additional orbital contribution. With the absence of a cooperative Jahn-Teller distortion, this points toward an orbital freezing. MnAl2O4 orders antiferromagnetically below TN=40K with a reduced value of the ordered moment and a large paramagnetic component. 

Cuvinte-cheie
magnetism, Curie Temperature, Antiferromagnet