Macroscopic behavior and microscopic magnetic properties of nanocarbon
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LÄHDERANTA, Erkki, RYZHOV, Vyacheslav, LASHKUL, Alexander V., GALIMOV, D., TITKOV, Alexander, MATVEEV, Vladimir, MOKEEV, Maxim, KURBAKOV, Alexander, LISUNOV, Konstantin. Macroscopic behavior and microscopic magnetic properties of nanocarbon. In: Journal of Magnetism and Magnetic Materials, 2015, vol. 383, pp. 78-82. ISSN 0304-8853. DOI: https://doi.org/10.1016/j.jmmm.2014.10.104
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Journal of Magnetism and Magnetic Materials
Volumul 383 / 2015 / ISSN 0304-8853

Macroscopic behavior and microscopic magnetic properties of nanocarbon

DOI:https://doi.org/10.1016/j.jmmm.2014.10.104
CZU: 537.8+621.38

Pag. 78-82

Lähderanta Erkki1, Ryzhov Vyacheslav1, Lashkul Alexander V.1, Galimov D.12, Titkov Alexander1, Matveev Vladimir34, Mokeev Maxim3, Kurbakov Alexander5, Lisunov Konstantin16
 
1 Lappeenranta University of Technology,
2 South Ural State University,
3 Institute of Macromolecular Compounds, Russian Academy of Sciences,
4 St Petersburg University,
5 Petersburg Nuclear Physics Institute, NRC “Kurchatov Institute”,
6 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 25 mai 2023


Rezumat

 Here are presented investigations of powder and glass-like samples containing carbon nanoparticles, not intentionally doped and doped with Ag, Au and Co. The neutron diffraction study reveals an amorphous structure of the samples doped with Au and Co, as well as the magnetic scattering due to a long-range FM order in the Co-doped sample. The composition and molecular structure of the sample doped with Au is clarified with the NMR investigations. The temperature dependence of the magnetization, M (T), exhibits large irreversibility in low fields of B=1-7 mT. M (B) saturates already above 2 T at high temperatures, but deviates from the saturation behavior below ~50 (150 K). Magnetic hysteresis is observed already at 300 K and exhibits a power-law temperature decay of the coercive field, Bc (T). The macroscopic behavior above is typical of an assembly of partially blocked magnetic nanoparticles. The values of the saturation magnetization, Ms, and the blocking temperature, Tb, are obtained as well. However, the hysteresis loop in the Co-doped sample differs from that in other samples, and the values of Bc and Ms are noticeably increased.

Cuvinte-cheie
magnetic properties, Nanocarbon, Neutron diffraction, NMR