Effect of Aggregation of Acridine Orange on the Luminescent Characteristics of Its Composites with a Zinc-Containing Coordination Polymer
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GURTOVYI, R., TSYMBAL, L., SHOVA, Sergiu, LAMPEKA, Yaroslaw. Effect of Aggregation of Acridine Orange on the Luminescent Characteristics of Its Composites with a Zinc-Containing Coordination Polymer. In: Theoretical and Experimental Chemistry, 2015, vol. 51, nr. 4, pp. 259-265. ISSN 0040-5760. DOI: https://doi.org/10.1007/s11237-015-9425-7
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Theoretical and Experimental Chemistry
Volumul 51, Numărul 4 / 2015 / ISSN 0040-5760 /ISSNe 1573-935X

Effect of Aggregation of Acridine Orange on the Luminescent Characteristics of Its Composites with a Zinc-Containing Coordination Polymer

DOI:https://doi.org/10.1007/s11237-015-9425-7

Pag. 259-265

Gurtovyi R.1, Tsymbal L.1, Shova Sergiu2, Lampeka Yaroslaw1
 
1 L.V. Pysarzhevskiy Institute of Physical Chemistry of National Academy of Sciences of Ukraine,
2 Institute of Chemistry of the Academy of Sciences of Moldova
 
 
Disponibil în IBN: 16 mai 2023


Rezumat

It was shown that the luminescent characteristics of the composites formed by the zinc-containing coordination polymer {[Zn(L)(NDC)]·0.5H2O}n (L = cyclam, NDC2– = 2,6-naphthalenedicarboxylate) with acridine orange depends on the ratio of the amounts of aggregated and isolated molecules of the dye, which in turn depends on the conditions under which the composites are produced. In all cases energy is transferred from the coordinated polymer to the dye, leading to bimodal luminescence in the composites. 

Cuvinte-cheie
acridine orange, bimodal luminescence, composites, coordination polymers, resonance energy transfer