Onset of exciton-exciton annihilation in single-layer black phosphorus
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SURRENTE, Alessandro, MITIOGLU, Anatolie, GALKOWSKI , Krzysztof, KLOPOTOWSKI, Lukasz, TABIS, Wojciech, VIGNOLLE, Baptiste, MAUDE, Duncan Kennedy, PŁOCHOCKA, Paulina. Onset of exciton-exciton annihilation in single-layer black phosphorus. In: Physical Review B, 2016, vol. 94, pp. 1-6. ISSN 2469-9950. DOI: https://doi.org/10.1103/PhysRevB.94.075425
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Physical Review B
Volumul 94 / 2016 / ISSN 2469-9950 /ISSNe 2469-9969

Onset of exciton-exciton annihilation in single-layer black phosphorus

DOI:https://doi.org/10.1103/PhysRevB.94.075425

Pag. 1-6

Surrente Alessandro1, Mitioglu Anatolie123, Galkowski Krzysztof1, Klopotowski Lukasz4, Tabis Wojciech51, Vignolle Baptiste1, Maude Duncan Kennedy1, Płochocka Paulina1
 
1 LNCMI, CNRS-UJF-UPS-INSA, Grenoble and Toulouse,
2 Institute of Applied Physics, Academy of Sciences of Moldova,
3 High Field Magnet Laboratory, Institute for Molecules and Materials, Radboud University,
4 Institute of Physics, Polish Academy of Science, Warsaw,
5 AGH University of Science and Technology, Krakow
 
 
Disponibil în IBN: 22 ianuarie 2023


Rezumat

The exciton dynamics in monolayer black phosphorus is investigated over a very wide range of photoexcited exciton densities using time resolved photoluminescence. At low excitation densities, the exciton dynamics is successfully described in terms of a double exponential decay. With increasing exciton population, a fast, nonexponential component develops as exciton-exciton annihilation takes over as the dominant recombination mechanism under high excitation conditions. Our results identify an upper limit for the injection density, after which exciton-exciton annihilation reduces the quantum yield, which will significantly impact the performance of light emitting devices based on single-layer black phosphorus.

Cuvinte-cheie
Double exponential, Excitation conditions, Excitation density, Exciton-exciton annihilation, Injection density, Light emitting devices, Recombination mechanisms, Time-resolved photoluminescence