| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 273 0 |
 SM ISO690:2012DARII, Mariana, NIRCA, Ecaterina, KRAVTSOV, Victor, BOUROSH, Pavlina, CHUMAKOV, Yurii, HAUSER, J, DECURTINS, Silvio, LIU, Shi-Xia, SULTANOVA, Olga, BACA, Svetlana. Crystalline multicomponent compounds involving hexaammine cobalt(III) cations. In: New Journal of Chemistry, 2022, nr. 23(46), pp. 11404-11421. ISSN 1144-0546. DOI: https://doi.org/10.1039/d2nj01655a |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
 New Journal of Chemistry |
||||||
| Numărul 23(46) / 2022 / ISSN 1144-0546 | ||||||
|
||||||
| DOI:https://doi.org/10.1039/d2nj01655a | ||||||
| Pag. 11404-11421 | ||||||
|
||||||
| Rezumat | ||||||
A new series of multicomponent compounds containing the cation [Co(NH3)6]3+ and various organic N-, N,O-, and O-donor moieties has been synthesized and crystallized. The series involves [Co(NH3)6]Cl3·2(phen)·3H2O (1), [Co(NH3)6](Hbdc)(bdc)·3H2O (2), [Co(NH3)6]Cl2(Hpht)·3H2O (3), [Co(NH3)6]Cl(Hpht)2·3H2O (4), [Co(NH3)6]Cl(2,3-pdc)·H2O (5), [Co(NH3)6]11[Co(2,5-pdc)3]8Cl·84H2O (6), [Co(NH3)6][Co(3,5-pdc)2(H2O)4]Cl·3H2O (7), [Co(NH3)6]Cl(sb)·4H2O (8), and [Co(NH3)6]2(sb)3·EtOH·2.5H2O (9) (where phen = 1,10-phenanthroline, H2bdc = diphenyl-4,4′-dicarboxylic acid, H2pht = o-phthalic acid, H2pdc = 2,3-/2,5-/3,5-pyridinedicarboxylic acid, H2sb = 4-sulfobenzoic acid). Single crystal X-ray diffraction studies have revealed that in these compounds the [Co(NH3)6]3+ cation serves as a building block for the incorporation of various anions/molecules and promotes the formation of multicomponent compounds with extended charge-supported networks between cations and anions and others such as H-bonds between charged⋯neutral and neutral⋯neutral components as well as π-π stacking interactions. In addition to the [Co(NH3)6]3+ cations, compounds 1-9 contain in changing composition Cl−, deprotonated phthalate, diphenyldicarboxylate, pyridinedicarboxylate, and sulfonate anions or complex [Co(2,5-pdc)3]4− and [Co(3,5-pdc)2(H2O)4]2− anions, as well as neutral 1,10-phenanthroline and ethanol and water molecules as components of the crystallization. Hirshfeld surface analysis was also performed to discuss the strength of hydrogen bonds and to quantify the inter-contacts. Energy decomposition analysis of the intermolecular interaction energy was performed using the SAPT method to study the non-covalent bonding interactions of [Co(NH3)6]3+ cations with mono-, dianions and neutral molecules, and it was found that the calculated bonding energy for compound 1 is minimal. Compounds 1-9 were tested in vitro against Rhizobium (Agrobacterium) vitis, an oncogenic bacterium that causes tumor formation in plants. Compound 1, comprising hexaammine cobalt(iii) chloride and 1,10-phenanthroline, showed the highest inhibitory potential and is thus qualified for an application against bacterial cancer in plants. |
||||||
| Cuvinte-cheie Ammonia, Carboxylation, Hydrogen bonds, Positive ions, single crystals |
||||||
|
Cerif XML Export
<?xml version='1.0' encoding='utf-8'?> <CERIF xmlns='urn:xmlns:org:eurocris:cerif-1.5-1' xsi:schemaLocation='urn:xmlns:org:eurocris:cerif-1.5-1 http://www.eurocris.org/Uploads/Web%20pages/CERIF-1.5/CERIF_1.5_1.xsd' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' release='1.5' date='2012-10-07' sourceDatabase='Output Profile'> <cfResPubl> <cfResPublId>ibn-ResPubl-167865</cfResPublId> <cfResPublDate>2022-05-23</cfResPublDate> <cfVol>46</cfVol> <cfIssue>23</cfIssue> <cfStartPage>11404</cfStartPage> <cfISSN>1144-0546</cfISSN> <cfURI>https://ibn.idsi.md/ro/vizualizare_articol/167865</cfURI> <cfTitle cfLangCode='EN' cfTrans='o'>Crystalline multicomponent compounds involving hexaammine cobalt(III) cations</cfTitle> <cfKeyw cfLangCode='EN' cfTrans='o'>Ammonia; Carboxylation; Hydrogen bonds; Positive ions; single crystals</cfKeyw> <cfAbstr cfLangCode='EN' cfTrans='o'><p>A new series of multicomponent compounds containing the cation [Co(NH<sub>3</sub>)<sub>6</sub>]<sup>3+</sup> and various organic N-, N,O-, and O-donor moieties has been synthesized and crystallized. The series involves [Co(NH<sub>3</sub>)<sub>6</sub>]Cl<sub>3</sub>·2(phen)·3H<sub>2</sub>O (1), [Co(NH<sub>3</sub>)<sub>6</sub>](Hbdc)(bdc)·3H<sub>2</sub>O (2), [Co(NH<sub>3</sub>)<sub>6</sub>]Cl<sub>2</sub>(Hpht)·3H<sub>2</sub>O (3), [Co(NH<sub>3</sub>)<sub>6</sub>]Cl(Hpht)<sub>2</sub>·3H<sub>2</sub>O (4), [Co(NH<sub>3</sub>)<sub>6</sub>]Cl(2,3-pdc)·H<sub>2</sub>O (5), [Co(NH<sub>3</sub>)<sub>6</sub>]<sub>11</sub>[Co(2,5-pdc)<sub>3</sub>]<sub>8</sub>Cl·84H<sub>2</sub>O (6), [Co(NH<sub>3</sub>)<sub>6</sub>][Co(3,5-pdc)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]Cl·3H<sub>2</sub>O (7), [Co(NH<sub>3</sub>)<sub>6</sub>]Cl(sb)·4H<sub>2</sub>O (8), and [Co(NH<sub>3</sub>)<sub>6</sub>]<sub>2</sub>(sb)<sub>3</sub>·EtOH·2.5H<sub>2</sub>O (9) (where phen = 1,10-phenanthroline, H<sub>2</sub>bdc = diphenyl-4,4′-dicarboxylic acid, H<sub>2</sub>pht = o-phthalic acid, H<sub>2</sub>pdc = 2,3-/2,5-/3,5-pyridinedicarboxylic acid, H<sub>2</sub>sb = 4-sulfobenzoic acid). Single crystal X-ray diffraction studies have revealed that in these compounds the [Co(NH<sub>3</sub>)<sub>6</sub>]<sup>3+</sup> cation serves as a building block for the incorporation of various anions/molecules and promotes the formation of multicomponent compounds with extended charge-supported networks between cations and anions and others such as H-bonds between charged⋯neutral and neutral⋯neutral components as well as π-π stacking interactions. In addition to the [Co(NH<sub>3</sub>)<sub>6</sub>]<sup>3+</sup> cations, compounds 1-9 contain in changing composition Cl<sup>−</sup>, deprotonated phthalate, diphenyldicarboxylate, pyridinedicarboxylate, and sulfonate anions or complex [Co(2,5-pdc)<sub>3</sub>]<sup>4−</sup> and [Co(3,5-pdc)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]<sup>2−</sup> anions, as well as neutral 1,10-phenanthroline and ethanol and water molecules as components of the crystallization. Hirshfeld surface analysis was also performed to discuss the strength of hydrogen bonds and to quantify the inter-contacts. Energy decomposition analysis of the intermolecular interaction energy was performed using the SAPT method to study the non-covalent bonding interactions of [Co(NH<sub>3</sub>)<sub>6</sub>]<sup>3+</sup> cations with mono-, dianions and neutral molecules, and it was found that the calculated bonding energy for compound 1 is minimal. Compounds 1-9 were tested in vitro against Rhizobium (Agrobacterium) vitis, an oncogenic bacterium that causes tumor formation in plants. Compound 1, comprising hexaammine cobalt(iii) chloride and 1,10-phenanthroline, showed the highest inhibitory potential and is thus qualified for an application against bacterial cancer in plants.</p></cfAbstr> <cfResPubl_Class> <cfClassId>eda2d9e9-34c5-11e1-b86c-0800200c9a66</cfClassId> <cfClassSchemeId>759af938-34ae-11e1-b86c-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfResPubl_Class> <cfResPubl_Class> <cfClassId>e601872f-4b7e-4d88-929f-7df027b226c9</cfClassId> <cfClassSchemeId>40e90e2f-446d-460a-98e5-5dce57550c48</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfResPubl_Class> <cfPers_ResPubl> <cfPersId>ibn-person-42282</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-97511</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-1035</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-197</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-991</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-15076</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-15079</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-54343</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-12643</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfPers_ResPubl> <cfPersId>ibn-person-211</cfPersId> <cfClassId>49815870-1cfe-11e1-8bc2-0800200c9a66</cfClassId> <cfClassSchemeId>b7135ad0-1d00-11e1-8bc2-0800200c9a66</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> </cfPers_ResPubl> <cfFedId> <cfFedIdId>ibn-doi-167865</cfFedIdId> <cfFedId>10.1039/d2nj01655a</cfFedId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFedId_Class> <cfClassId>31d222b4-11e0-434b-b5ae-088119c51189</cfClassId> <cfClassSchemeId>bccb3266-689d-4740-a039-c96594b4d916</cfClassSchemeId> </cfFedId_Class> <cfFedId_Srv> <cfSrvId>5123451</cfSrvId> <cfClassId>eda2b2e2-34c5-11e1-b86c-0800200c9a66</cfClassId> <cfClassSchemeId>5a270628-f593-4ff4-a44a-95660c76e182</cfClassSchemeId> </cfFedId_Srv> </cfFedId> </cfResPubl> <cfPers> <cfPersId>ibn-Pers-42282</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-42282-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Darii</cfFamilyNames> <cfFirstNames>Mariana</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-97511</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-97511-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Nirca</cfFamilyNames> <cfFirstNames>Ecaterina</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-1035</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-1035-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Kravtsov</cfFamilyNames> <cfFirstNames>Victor</cfFirstNames> <cfFamilyNames>Кравцов</cfFamilyNames> <cfFirstNames>Виктор</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-197</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-197-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Bourosh</cfFamilyNames> <cfFirstNames>Pavlina</cfFirstNames> <cfFamilyNames>Боурош</cfFamilyNames> <cfFirstNames>Павлина</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-991</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-991-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Chumakov</cfFamilyNames> <cfFirstNames>Yurii</cfFirstNames> <cfFamilyNames>Чумаков</cfFamilyNames> <cfFirstNames>Юрий</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-15076</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-15076-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Hauser</cfFamilyNames> <cfFirstNames>J</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-15079</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-15079-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Decurtins</cfFamilyNames> <cfFirstNames>Silvio</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-54343</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-54343-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Liu</cfFamilyNames> <cfFirstNames>Shi-Xia</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-12643</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-12643-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Султанова</cfFamilyNames> <cfFirstNames>О.</cfFirstNames> </cfPersName_Pers> </cfPers> <cfPers> <cfPersId>ibn-Pers-211</cfPersId> <cfPersName_Pers> <cfPersNameId>ibn-PersName-211-3</cfPersNameId> <cfClassId>55f90543-d631-42eb-8d47-d8d9266cbb26</cfClassId> <cfClassSchemeId>7375609d-cfa6-45ce-a803-75de69abe21f</cfClassSchemeId> <cfStartDate>2022-05-23T24:00:00</cfStartDate> <cfFamilyNames>Baca</cfFamilyNames> <cfFirstNames>Svetlana</cfFirstNames> </cfPersName_Pers> </cfPers> <cfSrv> <cfSrvId>5123451</cfSrvId> <cfName cfLangCode='en' cfTrans='o'>CrossRef DOI prefix service</cfName> <cfDescr cfLangCode='en' cfTrans='o'>The service of issuing DOI prefixes to publishers</cfDescr> <cfKeyw cfLangCode='en' cfTrans='o'>persistent identifier; Digital Object Identifier</cfKeyw> </cfSrv> </CERIF>
|
|
|
