Lattice modes and the Jahn-Teller ferroelectric transition of GaV4 S8
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HLINKA, Jiri, BORODAVKA, Fedir, RAFALOVSKYI, Iegor, DOCEKALOVA, Zuzana, POKORNY, Jan, GREGORA, Ivan, TSURKAN, Vladimir, NAKAMURA, Hiroyuki, MAYR, Franz, KUNTSCHER, Christine A., LOIDL, Alois, BORDACS, Sandor, SZALLER, David, LEE, Hyun-jae, LEE, Jun Hee, KEZSMARKI, Istvan. Lattice modes and the Jahn-Teller ferroelectric transition of GaV4 S8. In: Physical Review B, 2016, vol. 94, p. 0. ISSN 2469-9950. DOI: https://doi.org/10.1103/PhysRevB.94.060104
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Physical Review B
Volumul 94 / 2016 / ISSN 2469-9950 /ISSNe 2469-9969

Lattice modes and the Jahn-Teller ferroelectric transition of GaV4 S8

DOI:https://doi.org/10.1103/PhysRevB.94.060104

Pag. 0-0

Hlinka Jiri1, Borodavka Fedir1, Rafalovskyi Iegor1, Docekalova Zuzana1, Pokorny Jan1, Gregora Ivan, Tsurkan Vladimir23, Nakamura Hiroyuki4, Mayr Franz2, Kuntscher Christine A.2, Loidl Alois2, Bordacs Sandor5, Szaller David5, Lee Hyun-jae6, Lee Jun Hee6, Kezsmarki Istvan25
 
1 Institute of Physics of Academy of Sciences of the Czech Republic, Prague,
2 University of Augsburg,
3 Institute of Applied Physics, Academy of Sciences of Moldova,
4 Kyoto University,
5 Budapest University of Technology and Economics, Budapest,
6 Ulsan National Institute of Science and Technology
 
 
Disponibil în IBN: 14 septembrie 2022


Rezumat

Crystal of GaV4S8, a multiferroic system hosting a Néel-type skyrmion lattice phase, has been investigated by polarized Raman and IR spectroscopy above and below the ferroelectric phase transition. Counts of the observed IR and Raman-active modes belonging to distinct irreducible representations agree quite well with group-theory predictions. Phonon spectra are assigned and interpreted with the aid of ab initio calculations of the phonon spectra in the ferroelectric phase. Results allow appreciation of phonon frequencies of the modes involved in Jahn-Teller distortion and their contribution to the spontaneous polarization. 

Cuvinte-cheie
Binary alloys, Calculations, Ferroelectricity, Gallium alloys, Group theory, Jahn-Teller effect, phonons, Vanadium alloys