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SM ISO690:2012 EFTHIMIOPOULOS, Ilias, LOCHBILER, Thomas A., TSURKAN, Vladimir, LOIDL, Alois, FELEA, Viorel, WANG, Yuejian. Structural behavior of ZnCr2S4 spinel under pressure. In: Journal of Physical Chemistry C, 2017, vol. 121, pp. 769-777. ISSN 1932-7447. DOI: https://doi.org/10.1021/acs.jpcc.6b11253 |
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Journal of Physical Chemistry C | ||||||
Volumul 121 / 2017 / ISSN 1932-7447 /ISSNe 1932-7455 | ||||||
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DOI:https://doi.org/10.1021/acs.jpcc.6b11253 | ||||||
Pag. 769-777 | ||||||
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The series of Cr-chalcogenide spinels ACr2X4 (A = Zn, Cd, Hg; X = S, Se) exhibits a rich phase diagram upon compression, as revealed by our recent investigations. There exist, however, some open questions regarding the role of cations in the observed structural transitions. In order to address these queries, we have performed X-ray diffraction and Raman spectroscopic studies on the ZnCr2S4 spinel up to 42 GPa, chosen mainly due to the similarity of the Zn2+ and Cr3+ cationic radii. Two reversible structural transitions were identified at 22 and 33 GPa, into a I41/amd and an orthorhombic phase, respectively. Close comparison with the behavior of relevant Cr-spinels revealed that the structural transitions are mainly governed by the competition of the magnetic exchange interactions present in these systems, and not by steric effects. In addition, careful inspection of the starting Fd3m phase revealed a previously unnoticed isostructural transition. The latter is intimately related to changes in the electronic properties of these systems, as evidenced by our Raman studies. Our results provide insights for tuning the physical and chemical properties of these materials, even under moderate compression, as well as promoting the understanding of similar pressure-induced effects in relevant systems. |
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Cuvinte-cheie Chromium compounds, Chromium metallography, Electronic properties, Spectroscopic analysis, Zinc compounds, Zinc metallography |
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