Conţinutul numărului revistei |
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256 0 |
SM ISO690:2012 PODGORNÎI, Daniel, VAN LEUSEN, Jan, KRAVTSOV, Victor, KOGERLER, Paul, BACA, Svetlana. A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains. In: CrystEngComm, 2021, vol. 23, pp. 5153-5156. ISSN 1466-8033. DOI: https://doi.org/10.1039/d1ce00777g |
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CrystEngComm | ||||||
Volumul 23 / 2021 / ISSN 1466-8033 | ||||||
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DOI:https://doi.org/10.1039/d1ce00777g | ||||||
Pag. 5153-5156 | ||||||
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Rezumat | ||||||
Charge-neutral [Na2Fe10O6(OH)4(isobutyrate)14(MeO)2(MeCN)2] coordination clusters, comprising a hollow ‘Chinese lantern’-like shell of six condensed planar triangular {FeIII3(μ3-O)} motifs, form upon ultrasonication of trinuclear Fe(iii) isobutyrate units in acetonitrile in the presence of sodium azide and 4,4′-bipyridine (bpy), resulting in {[Na2Fe10O6(OH)4(isobutyrate)14(bpy)(MeO)2(MeCN)2]·MeOH}nin which the dodecanuclear cluster units are bpy-bridged into 1D chains. |
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