Ammonia, originated from the decomposition of organic matter, being the richest natural substance in nitrogen, with the exception of that molecule, is non-toxic for a wide range of bacteria at the level of a few mol/L, unlike animal and plant cells. In this paper, the difference in the impact of amines of natural origin (diethylamine, DEA) and synthetic origin (1-naphtylamine, 1-NA and diphenylamine, DFA) on the processes of ammonia oxidation has been investigated. 1-NA significantly inhibited nitrification by a mixed population of Nitrobacter and Nitrosomonas species isolated from activated sludge; a concentration of 15 mg/L gave a 50% inhibition. Maximum admissible concentrations (MAC) for 1-NA and DEA differs by two orderd. The laboratory simulations have been carried out in water of the Nistru River (in the section of the Vadul-lui-Voda town). To river water samples of water, the NH4Cl solution has been added, in order to achiieve concentrations of ~ 3.2 mg/L and ~ 6.4 mg/L of ammonium, which are characteristic for rain water and a series of contaminated objects. Both DEA and 1-NA influence in the redox processes generated by bacterial enzyme activity even within the MAC values. In the case of 1-NA the braking effect is related to the toxic effect, while for DEA this effect is doubled (due to the toxic effect and also that related to the aminic carbon). It has been shown that the aminic nitrogen exhibits more pronounced toxic effects in comparison with ammonia. Typically, the amines, originated from the decomposition of organic materials of natural origin, have less toxicity and lower MACs by about ten times higher than those of synthetic origin. Here, it is important to mention that laboratory models are sensitive even at concentrations below MAC.
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