| Articolul precedent |
| Articolul urmator |
 |
 534 7 |
| Ultima descărcare din IBN: 2024-03-22 05:47 |
 SM ISO690:2012EDDAOUDI, Mohamed, LIU, Yong-Lin, KRAVTSOV, Victor, LARSEN, Randy William. Molecular building block approach to the assembly of zeolitelike metal-organic frameworks (ZMOFs) with extra-large cavities. In: Physical Methods in Coordination and Supramolecular Chemistry, 27 septembrie - 1 octombrie 2006, Chişinău. Chisinau, Republic of Moldova: 2006, XVII, p. 28. ISBN 978-9975-62-066-6. |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
| Physical Methods in Coordination and Supramolecular Chemistry XVII, 2006 |
||||||
|
Conferința "The XV-th International Conference Physical Methods in Coordination and Supramolecular Chemistry : The XVII-th Reading in memory of Acad. A.Ablov" Chişinău, Moldova, 27 septembrie - 1 octombrie 2006 | ||||||
|
||||||
| Pag. 28-28 | ||||||
|
||||||
 Descarcă PDF |
||||||
| Rezumat | ||||||
Molecular building blocks (MBBs) have been utilized previously as components in the design and synthesis of novel metal-organic frameworks (MOFs), most based on the assembly of metalcarboxylate clusters and polytopic organic ligands of various shapes. Here we introduce the use of the MBB approach in the rational assembly of pre-designed polytopic organic linkers and heterocoordinated single metal, MNxOy -type, clusters into new zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities. Three novel porous anionic ZMOFs, rho-ZMOF, sod-ZMOF and usf-ZMOF, have been constructed by metal-ligand directed assembly of rigid and directional tetrahedral building units, InN4 synthesized in-situ, and doubly deprotonated bis(bidentate) imidazoledicarboxylic acid ligands (HImDC) in the presence of different structure directing agents (SDAs). The design strategy, synthesis, structure, porosity, and their inclusion and sensing chemistry will be discussed. |
||||||
|
Dublin Core Export
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Eddaoudi, M.</dc:creator> <dc:creator>Liu, Y.</dc:creator> <dc:creator>Kravţov, V.H.</dc:creator> <dc:creator>Larsen, R.</dc:creator> <dc:date>2006</dc:date> <dc:description xml:lang='en'><p>Molecular building blocks (MBBs) have been utilized previously as components in the design and synthesis of novel metal-organic frameworks (MOFs), most based on the assembly of metalcarboxylate clusters and polytopic organic ligands of various shapes. Here we introduce the use of the MBB approach in the rational assembly of pre-designed polytopic organic linkers and heterocoordinated single metal, MNxOy -type, clusters into new zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities. Three novel porous anionic ZMOFs, rho-ZMOF, sod-ZMOF and usf-ZMOF, have been constructed by metal-ligand directed assembly of rigid and directional tetrahedral building units, InN4 synthesized in-situ, and doubly deprotonated bis(bidentate) imidazoledicarboxylic acid ligands (HImDC) in the presence of different structure directing agents (SDAs). The design strategy, synthesis, structure, porosity, and their inclusion and sensing chemistry will be discussed.</p></dc:description> <dc:source>Physical Methods in Coordination and Supramolecular Chemistry (XVII) 28-28</dc:source> <dc:title>Molecular building block approach to the assembly of zeolitelike metal-organic frameworks (ZMOFs) with extra-large cavities</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>
|
|
|
