Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
1095 2 |
Ultima descărcare din IBN: 2018-07-20 19:07 |
SM ISO690:2012 COROPCEANU, Eduard, CROITOR, Lilia, DESYATNIK, A., CLAPCO, Steliana, LABLYUK, S., CODREANU, Svetlana, FONARI, Marina. Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2017, vol. 43, pp. 433-440. ISSN -. DOI: https://doi.org/10.1134/S1070328417070053 |
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya | |
Volumul 43 / 2017 / ISSN - /ISSNe 1070-3284 | |
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DOI:https://doi.org/10.1134/S1070328417070053 | |
Pag. 433-440 | |
Rezumat | |
The complexes [Zn(CH3COO)2(NioxH2)(DMF)(H2O)] (I), [Cd(CH3COO)2-(NioxH2)(DMF)(H2O)] (II), [Zn(CH3COO)2(NioxH2)(S-Nia)(H2O)] · DMF (III), [Zn(CH3COO)2(NioxH2)(Nia)(H2O)] (IV), and [Zn(CH3COO)2(NioxH2)(INia)(H2O)] (V), where NioxH2 is 1,2-cyclohexanedione dioxime, S-Nia is thionicotinamide, Nia is nicotinamide, and INia is iso-nicotinamide, were prepared and investigated. Compounds I–III were studied by X-ray diffraction (CCDC nos. 1505280–1505282 for I–III, respectively). Testing of zinc complexes containing various ligands demonstrated that at the optimized concentration (5 mg/L), they can be used for stimulating biosynthesis of both standard (57.14%, pH 4.7) and acid-labile (17.63%, pH 2.5) amylases by the micromycete Aspergillus niger CNMN FD 06 without affecting the duration of producer culturing. |
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Cuvinte-cheie 1, coordination compounds, crystal structure |
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<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Coropceanu, E.B.</dc:creator> <dc:creator>Croitor, L.M.</dc:creator> <dc:creator>Ciloci (Deseatnic), A.A.</dc:creator> <dc:creator>Clapco, S.F.</dc:creator> <dc:creator>Labliuc, S.V.</dc:creator> <dc:creator>Codreanu, S.N.</dc:creator> <dc:creator>Fonari, M.S.</dc:creator> <dc:date>2017-07-01</dc:date> <dc:description xml:lang='en'><p>The complexes [Zn(CH<sub>3</sub>COO)<sub>2</sub>(NioxH<sub>2</sub>)(DMF)(H<sub>2</sub>O)] (I), [Cd(CH<sub>3</sub>COO)<sub>2</sub>-(NioxH<sub>2</sub>)(DMF)(H<sub>2</sub>O)] (II), [Zn(CH<sub>3</sub>COO)<sub>2</sub>(NioxH<sub>2</sub>)(S-Nia)(H<sub>2</sub>O)] · DMF (III), [Zn(CH<sub>3</sub>COO)<sub>2</sub>(NioxH<sub>2</sub>)(Nia)(H<sub>2</sub>O)] (IV), and [Zn(CH<sub>3</sub>COO)<sub>2</sub>(NioxH<sub>2</sub>)(INia)(H<sub>2</sub>O)] (V), where NioxH<sub>2</sub> is 1,2-cyclohexanedione dioxime, S-Nia is thionicotinamide, Nia is nicotinamide, and INia is iso-nicotinamide, were prepared and investigated. Compounds I–III were studied by X-ray diffraction (CCDC nos. 1505280–1505282 for I–III, respectively). Testing of zinc complexes containing various ligands demonstrated that at the optimized concentration (5 mg/L), they can be used for stimulating biosynthesis of both standard (57.14%, pH 4.7) and acid-labile (17.63%, pH 2.5) amylases by the micromycete Aspergillus niger CNMN FD 06 without affecting the duration of producer culturing.</p></dc:description> <dc:identifier>10.1134/S1070328417070053</dc:identifier> <dc:source>Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya () 433-440</dc:source> <dc:subject>1</dc:subject> <dc:subject>coordination compounds</dc:subject> <dc:subject>crystal structure</dc:subject> <dc:title>Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>