Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines
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COROPCEANU, Eduard, CROITOR, Lilia, DESYATNIK, A., CLAPCO, Steliana, LABLYUK, S., CODREANU, Svetlana, FONARI, Marina. Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2017, vol. 43, pp. 433-440. ISSN -. DOI: https://doi.org/10.1134/S1070328417070053
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volumul 43 / 2017 / ISSN - /ISSNe 1070-3284

Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines

DOI:https://doi.org/10.1134/S1070328417070053

Pag. 433-440

Coropceanu Eduard12, Croitor Lilia3, Desyatnik A.3, Clapco Steliana4, Lablyuk S.3, Codreanu Svetlana2, Fonari Marina3
 
1 Institute of Chemistry of the Academy of Sciences of Moldova,
2 Tiraspol State University,
3 Institute of Applied Physics, Academy of Sciences of Moldova,
4 Institute of Microbiology and Biotechnology of the ASM
 
 
Disponibil în IBN: 16 februarie 2018


Rezumat

The complexes [Zn(CH3COO)2(NioxH2)(DMF)(H2O)] (I), [Cd(CH3COO)2-(NioxH2)(DMF)(H2O)] (II), [Zn(CH3COO)2(NioxH2)(S-Nia)(H2O)] · DMF (III), [Zn(CH3COO)2(NioxH2)(Nia)(H2O)] (IV), and [Zn(CH3COO)2(NioxH2)(INia)(H2O)] (V), where NioxH2 is 1,2-cyclohexanedione dioxime, S-Nia is thionicotinamide, Nia is nicotinamide, and INia is iso-nicotinamide, were prepared and investigated. Compounds I–III were studied by X-ray diffraction (CCDC nos. 1505280–1505282 for I–III, respectively). Testing of zinc complexes containing various ligands demonstrated that at the optimized concentration (5 mg/L), they can be used for stimulating biosynthesis of both standard (57.14%, pH 4.7) and acid-labile (17.63%, pH 2.5) amylases by the micromycete Aspergillus niger CNMN FD 06 without affecting the duration of producer culturing.

Cuvinte-cheie
1, coordination compounds, crystal structure

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<dc:creator>Coropceanu, E.B.</dc:creator>
<dc:creator>Croitor, L.M.</dc:creator>
<dc:creator>Ciloci (Deseatnic), A.A.</dc:creator>
<dc:creator>Clapco, S.F.</dc:creator>
<dc:creator>Labliuc, S.V.</dc:creator>
<dc:creator>Codreanu, S.N.</dc:creator>
<dc:creator>Fonari, M.S.</dc:creator>
<dc:date>2017-07-01</dc:date>
<dc:description xml:lang='en'><p>The complexes [Zn(CH<sub>3</sub>COO)<sub>2</sub>(NioxH<sub>2</sub>)(DMF)(H<sub>2</sub>O)] (I), [Cd(CH<sub>3</sub>COO)<sub>2</sub>-(NioxH<sub>2</sub>)(DMF)(H<sub>2</sub>O)] (II), [Zn(CH<sub>3</sub>COO)<sub>2</sub>(NioxH<sub>2</sub>)(S-Nia)(H<sub>2</sub>O)] &middot; DMF (III), [Zn(CH<sub>3</sub>COO)<sub>2</sub>(NioxH<sub>2</sub>)(Nia)(H<sub>2</sub>O)] (IV), and [Zn(CH<sub>3</sub>COO)<sub>2</sub>(NioxH<sub>2</sub>)(INia)(H<sub>2</sub>O)] (V), where NioxH<sub>2</sub> is 1,2-cyclohexanedione dioxime, S-Nia is thionicotinamide, Nia is nicotinamide, and INia is iso-nicotinamide, were prepared and investigated. Compounds I&ndash;III were studied by X-ray diffraction (CCDC nos. 1505280&ndash;1505282 for I&ndash;III, respectively). Testing of zinc complexes containing various ligands demonstrated that at the optimized concentration (5 mg/L), they can be used for stimulating biosynthesis of both standard (57.14%, pH 4.7) and acid-labile (17.63%, pH 2.5) amylases by the micromycete Aspergillus niger CNMN FD 06 without affecting the duration of producer culturing.</p></dc:description>
<dc:identifier>10.1134/S1070328417070053</dc:identifier>
<dc:source>Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya  () 433-440</dc:source>
<dc:subject>1</dc:subject>
<dc:subject>coordination compounds</dc:subject>
<dc:subject>crystal structure</dc:subject>
<dc:title>Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
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