Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly: Via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions

Ayhan Mehmet Menaf; Ozcan Emrah; Dedeoglu Burcu; Chumakov Yurii; Zorlu Yunus; Cosut Bunyemin

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386

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AYHAN, Mehmet Menaf, OZCAN, Emrah, DEDEOGLU, Burcu, CHUMAKOV, Yurii, ZORLU, Yunus, COSUT, Bunyemin. Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly: Via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions. In: CrystEngComm, 2021, vol. 23, pp. 268-272. ISSN 1466-8033. DOI: https://doi.org/10.1039/d0ce01640c

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CrystEngComm

Volumul 23 / 2021 / ISSN 1466-8033

Carbon (sp³) tetrel bonding mediated BODIPY supramolecular assembly: Via unprecedented synergy of C_sp3⋯N and C_sp3⋯F pair interactions

DOI:https://doi.org/10.1039/d0ce01640c

Pag. 268-272

Ayhan Mehmet Menaf¹, Ozcan Emrah¹², Dedeoglu Burcu¹, Chumakov Yurii¹³, Zorlu Yunus¹, Cosut Bunyemin¹

¹ Gebze Technical University,
² University of South Bohemia in České Budějovice,
³ Institute of Applied Physics

Disponibil în IBN: 4 aprilie 2021

Rezumat

Here, we present the first example of sp3 hybridized carbon centered (Csp3) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of Csp3⋯N and Csp3⋯F pair interactions. The carbon tetrel bond interaction energies of Csp3⋯N and Csp3⋯F are amplified significantly as the size of the 1D chain grows from dimer to tetramer BODIPY units.

Cuvinte-cheie
1-D chains, Bond interactions, Pair interactions, Supramolecular assemblies, Tetramers

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<dc:creator>Ayhan, M.</dc:creator>
<dc:creator>Ozcan, E.</dc:creator>
<dc:creator>Dedeoglu, B.</dc:creator>
<dc:creator>Ciumacov, I.M.</dc:creator>
<dc:creator>Zorlu, Y.</dc:creator>
<dc:creator>Cosut, B.</dc:creator>
<dc:date>2021-01-14</dc:date>
<dc:description xml:lang='en'><p>Here, we present the first example of sp3 hybridized carbon centered (Csp3) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of Csp3⋯N and Csp3⋯F pair interactions. The carbon tetrel bond interaction energies of Csp3⋯N and Csp3⋯F are amplified significantly as the size of the 1D chain grows from dimer to tetramer BODIPY units.</p></dc:description>
<dc:identifier>10.1039/d0ce01640c</dc:identifier>
<dc:source>CrystEngComm  () 268-272</dc:source>
<dc:subject>1-D chains</dc:subject>
<dc:subject>Bond interactions</dc:subject>
<dc:subject>Pair interactions</dc:subject>
<dc:subject>Supramolecular assemblies</dc:subject>
<dc:subject>Tetramers</dc:subject>
<dc:title>Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly: Via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions</dc:title>
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