Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly: Via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions

Ayhan Mehmet Menaf; Dedeoglu Burcu; Chumakov Yurii; Zorlu Yunus; Cosut Bunyemin

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AYHAN, Mehmet Menaf, , , DEDEOGLU, Burcu, CHUMAKOV, Yurii, ZORLU, Yunus, COSUT, Bunyemin. Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly: Via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions. In: CrystEngComm, 2021, vol. 23, pp. 268-272. ISSN 1466-8033. DOI: https://doi.org/10.1039/d0ce01640c

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CrystEngComm

Volumul 23 / 2021 / ISSN 1466-8033

Carbon (sp³) tetrel bonding mediated BODIPY supramolecular assembly: Via unprecedented synergy of C_sp3⋯N and C_sp3⋯F pair interactions

DOI:https://doi.org/10.1039/d0ce01640c

Pag. 268-272

Ayhan Mehmet Menaf¹, ¹², Dedeoglu Burcu¹, Chumakov Yurii¹³, Zorlu Yunus¹, Cosut Bunyemin¹

¹ Gebze Technical University,
² University of South Bohemia in České Budějovice,
³ Institute of Applied Physics

Disponibil în IBN: 4 aprilie 2021

Rezumat

Here, we present the first example of sp3 hybridized carbon centered (Csp3) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of Csp3⋯N and Csp3⋯F pair interactions. The carbon tetrel bond interaction energies of Csp3⋯N and Csp3⋯F are amplified significantly as the size of the 1D chain grows from dimer to tetramer BODIPY units.

Cuvinte-cheie
1-D chains, Bond interactions, Pair interactions, Supramolecular assemblies, Tetramers

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