Ultradispersed copper-bearing powders have been produced by the method of electrochemical cathode reduction from water–isopropanol solutions of copper dichloride. The dimensional and morphological properties of the obtained compounds have been studied using the procedure of atomic-power microscopy. It is shown that the introduction of isopropyl alcohol additions into the aqueous electrolyte composition causes a change of both the dimensional and qualitative features of the powders. The isopropyl alcohol admixture shifts the ratio between the components entering into the composition of the copper-bearing powders towards a greater content of copper oxide (I).