The production of the multifunctional additives for diesel fuels on the basis of vegetable bioresources
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2024-02-05 13:00
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MAMMADOVA, Tarana, ABBASOV, Mutallim, NAMAZOV, Anar, ABBASOV, Vagif. The production of the multifunctional additives for diesel fuels on the basis of vegetable bioresources. In: Ecological and environmental chemistry : - 2017, Ed. 6, 2-3 martie 2017, Chișinău. Chisinau, Republic of Moldova: Academy of Sciences of Moldova, 2017, Ediția 6, p. 219.
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Ecological and environmental chemistry
Ediția 6, 2017
Conferința "Ecological and environmental chemistry 2017"
6, Chișinău, Moldova, 2-3 martie 2017

The production of the multifunctional additives for diesel fuels on the basis of vegetable bioresources


Pag. 219-219

Mammadova Tarana, Abbasov Mutallim, Namazov Anar, Abbasov Vagif
 
Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan
 
 
Disponibil în IBN: 19 martie 2019


Rezumat

In this proceeding, the production process of the biodiesel ethers based on corn and sunflower oil and methanol in magnetic field with an intensity of 15-45mT at 65°C temperature with 6:1 ratio of methanol to oil by using synthesized 1,3-bis (isopropylamino)-propan-2-ol as catalyst has been investigated. The experiments were operated in three-neck round-bottom flask which is placed in magnetic field produced by electromagnets and equipped with thermometer, mixer and dropping funnel. The amount of catalyst (according to oil) was in the interval of 1-3%. Refined corn and sunflower oils and unrefined sunflower oil were used as vegetable oils. When the duration of the process is 40 minutes, the yields of biodiesel ethers are in the interval of 22-26% (by mass) in normal conditions by using new synthesized 1,3-bis (isopropylamino)-propan-2-ol catalyst with 1% mass. However, when the magnetic field is applied, the yields are doubled in the same duration, they were 43-46% (by mass). The yields of biodiesel ethers are 43-48% and 58-62% during 2 and 4 hours respectively, whereas the same pointers are 62-68% and 72-81% (by mass) in the presence of magnetic field. As a result of the experiments, it was revealed that, if the amount of catalyst is increased to 3%, 95-97% (by mass) yield is obtained during 40 minutes under magnetic field. However, under standard conditions, the same indicator is 61-65% and even during 4 hours, it is 90-91% (by mass). Produced biodiesel ethers have been added to mineral based diesel fuel by 5% and 10% and the properties of these compounds and flue gases have been investigeted. As it is obvious from the presented information, for 5-10% compounds, decreases of 24,7 -40,3 %, 6,8-11,0 % and 9,8 -10,5 % (by mass) have been recorded for CO, NOx and SO2 gases respectively. The content of flue gases, % mass CO SO2 NOx Primary mineral diesel fuel 0,575 0,058 0,051 After addition of 5% biodiesel 0,434 0,054 0,046 After addition of 10% biodiesel 0,358 0,053 0,045 Besides that, the smoking ability of produced compounds has been determined by “Smokemeter 495/01” device in the Laboratory of Ecological Control of Transport Vehicles in the Department of Ecology in SOCAR and 44% decrease has been observed for 10% compounds. At the same time, for 5-10% compounds, wear scar diameter is 460mic by decreasing 24-45% in diesel engines.