Multiwavelength excitation Raman scattering of Cu2ZnSn1-xGex(S,Se)4single crystals for earth abundant photovoltaic applications
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GARCIA-LLAMAS, E., GUK, Maxim, BODNAR, Ivan V., FONTANE, Xavier, CABALLERO, Raquel, MERINO, Jose Manuel, LEON, Maximo, IZQUIERDO-ROCA, Víctor. Multiwavelength excitation Raman scattering of Cu2ZnSn1-xGex(S,Se)4single crystals for earth abundant photovoltaic applications. In: Journal of Alloys and Compounds, 2017, vol. 692, pp. 249-256. ISSN 0925-8388. DOI: https://doi.org/10.1016/j.jallcom.2016.09.035
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Journal of Alloys and Compounds
Volumul 692 / 2017 / ISSN 0925-8388

Multiwavelength excitation Raman scattering of Cu2ZnSn1-xGex(S,Se)4single crystals for earth abundant photovoltaic applications

DOI:https://doi.org/10.1016/j.jallcom.2016.09.035

Pag. 249-256

Garcia-Llamas E.1, Guk Maxim2, Bodnar Ivan V.3, Fontane Xavier2, Caballero Raquel1, Merino Jose Manuel1, Leon Maximo1, Izquierdo-Roca Víctor2
 
1 Universidad Autónoma de Madrid,
2 Catalonia Institute for Energy Research (IREC), Barcelona,
3 Belarusian State University of Informatics and Radioelectronics
 
 
Disponibil în IBN: 17 decembrie 2018


Rezumat

Raman spectroscopy was used to evaluate the zone-center optical phonons of Cu2ZnSn1-xGex(S,Se)4single crystals, leading to a complete characterization of their vibrational properties. High quality of the samples grown by chemical vapour transport was approved by analysis of X-ray dispersion and diffraction spectra. The analysis has been performed by using Raman scattering excited with different wavelengths, which allowed presenting the fingerprint spectra of the solid solutions in the resonant and non-resonant conditions. The Raman spectra show more than 30 characteristic peaks for different Cu2ZnSn1-xGexS4and Cu2ZnSn1-xGexSe4samples. The two mode behavior was found for most of the peaks in both solutions. However, the most intense mode exhibited one mode behavior in selenium containing compounds and two mode behavior in sulfur containing compounds. Possible reasons for this difference are discussed.

Cuvinte-cheie
Cu2ZnSn1-xGex(S,Se)4, Fingerprint spectra, XRD, Raman spectroscopy, single crystals