Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
27 0 |
SM ISO690:2012 KULYUK, Leonid, POPOV, Serghei, OSTROVSKY, Sergei M., PALII, Andrew, TSUKERBLAT, Boris S.. Pseudo-Jahn-Teller Vibronic Model of a Cubic 3d3 Impurity in Crystals. Luminescence of CdIn2S4:Cr3+. In: Zeitschrift fur Physikalische Chemie, 1996, vol. 1, pp. 319-323. ISSN 0942-9352. DOI: https://doi.org/10.1524/zpch.1996.1.1.319 |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
Zeitschrift fur Physikalische Chemie | ||||||
Volumul 1 / 1996 / ISSN 0942-9352 /ISSNe 2196-7156 | ||||||
|
||||||
DOI:https://doi.org/10.1524/zpch.1996.1.1.319 | ||||||
Pag. 319-323 | ||||||
|
||||||
Rezumat | ||||||
A new model for the vibronic problem of luminescence of 3d3 impurity ions in the cubic environment is proposed. The approach developed is based on the numerical quantum-mechanical solution of the dynamic pseudo Jahn-Teller vibronic problem for the excited states. Spin-orbit splitting of 4T2 term and its mixing with 2E as well as the vibronic interaction with the full-symmetric (A1g) local mode is taken into account resulting in the [formula omitted] vibronic problem and [formula omitted], adiabatic problems. The band shape of the luminescence and the temperature dependence of the life-time decay emission are evaluated for Cr3+ ions in CdIn2S4:Cr single crystals. The proposed model provides a very good explanation of the experimental data. |
||||||
Cuvinte-cheie Tetraborate, Spectacles, ion |
||||||
|