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65 0 |
SM ISO690:2012 TSUKERBLAT, Boris S., PALII, Andrew, OSTROVSKY, Sergei M., KULYUK, Leonid, POPOV, Serghei. A pseudo-Jahn-Teller vibronic model of d3 ions in cubic crystals; the luminescence band shape and lifetimes of CdIn2S4:Cr3+. In: Journal of Physics Condensed Matter, 1997, vol. 9, pp. 5295-5312. ISSN 0953-8984. DOI: https://doi.org/10.1088/0953-8984/9/25/001 |
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Journal of Physics Condensed Matter | ||||||
Volumul 9 / 1997 / ISSN 0953-8984 /ISSNe 1361-648X | ||||||
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DOI:https://doi.org/10.1088/0953-8984/9/25/001 | ||||||
Pag. 5295-5312 | ||||||
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A new model for the vibronic problem of the luminescence of 3d3 impurity ions in the cubic environment is proposed. The approach developed is based on the numerical quantum-mechanical solution of the dynamic pseudo-Jahn-Teller vibronic problem for the excited states. The spin-orbit splitting of the 4T2 term, and its mixing with 2E, as well as the vibronic interaction with the full-symmetric (A1g) local mode, are taken into account, resulting in the (Γ8+Γ8′+Γ8″) ⊗a1 vibronic problem, and the Γ6⊗ a1 and Γ7⊗a1 adiabatic problems. The effective dipole moment operator is built with due regard for a weak odd-parity trigonal crystal-field component. The vibronic wave-functions are used for the calculation of the band shape of the luminescence in the R line and U band, as well as for the evaluation of the temperature dependence of the lifetime decay emission of Cr3+ ions in CdIn2S4:Cr single crystals. The proposed model provides a very good explanation of the experimental data. |
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