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 SM ISO690:2012STORCH, Herbert, CONSTANTINESCU, Elena, ANDREI, Monica, DIMA, Gabriela E., TURTA, Constantin, LAZARESKU, Ana. Cyclic voltammetric study of the trinuclear complexes [Fe 3O(CH3COO)6(H2O)3]NO 3 and [Fe3O(+H3NCH 2COO-)6(H2O)3](NO 3)7. In: Revue Roumaine de Chimie, 2002, vol. 47, pp. 67-70. ISSN 0035-3930. |
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  Revue Roumaine de Chimie |
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| Volumul 47 / 2002 / ISSN 0035-3930 | ||||||
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| Pag. 67-70 | ||||||
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The homotrinuclear coordination compounds [Fe3O(CH 3COO)6H2O)3]NO3 and [Fe3O(CH3COO3)6(H2O) 3]NO3)7 were studied by cyclic voltammetry at stationary platinum electrode in dimethylsulfoxide with 0.1 M tetrabutylammoniumperchlorate as supporting electrolyte in order to sustain results of MO calculations performed on the two complexes. The potentials for the electrode processes visualized by the first voltammetric reduction wave are close for the two complexes. In an extended potential range (from +0.4 to -0.9V), the acetate bridged complex shows one and the glicine bridged complex shows two additional irreversible waves. |
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| Cuvinte-cheie Engineering controlled terms Data reduction, Electrodes, Electrolytes, hydrogen, Platinum, Rate constants, Synthesis (chemical), Water Engineering uncontrolled terms Electronic energetic levels, Ion charges, Irreversible waves, Voltammetry Engineering main heading Iron compounds |
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