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SM ISO690:2012 MERIAKRE, V., NAKANO, Motohiro, GOMEZ-SEGURA, Jordi, IMAZ, Inhar, SPORER, Christian, WURST, Klaus, VECIANA, Jaume, TURTA, Constantin, RUIZ-MOLINA, Daniel, JAITNER, Peter E.. A new hexaferrocene complex with a [M3(μ3-O)] 7+ core. In: Inorganic Chemistry, 2006, vol. 45, pp. 10443-10445. ISSN 0020-1669. DOI: https://doi.org/10.1021/ic061322s |
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Inorganic Chemistry | ||||||
Volumul 45 / 2006 / ISSN 0020-1669 | ||||||
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DOI:https://doi.org/10.1021/ic061322s | ||||||
Pag. 10443-10445 | ||||||
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The new hexaferrocene complex 1 has been synthesized and characterized by X-ray diffraction. Its magnetization data were fitted to a detailed theoretical model that considers nonequivalent exchange parameters between Fe ions to yield the magnetic exchange coupling values of J1/kB = -31.5 K and J2/kB = -25.8 K. Moreover, the cyclic voltammogram of complex 1 confirmed its redox activity associated with the presence of ferrocene units, with very small or negligible electronic interactions between them. |
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