| Conţinutul numărului revistei |
| Articolul precedent |
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 SM ISO690:2012GRINCO, Marina, GÎRBU, Vladilena, GORINCIOI, Elena, BARBA, Alic, KULCIŢKI, Veaceslav, UNGUR, Nikon. The first biomimetic synthesis of a diterpenoid with the ent-verrucosin A/B skeleton. In: Tetrahedron Letters, 2016, nr. 19(57), pp. 2084-2096. ISSN 0040-4039. DOI: https://doi.org/10.1016/j.tetlet.2016.03.106 |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
 Tetrahedron Letters |
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| Numărul 19(57) / 2016 / ISSN 0040-4039 | ||||||
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| DOI:https://doi.org/10.1016/j.tetlet.2016.03.106 | ||||||
| Pag. 2084-2096 | ||||||
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| Rezumat | ||||||
The first biomimetic synthesis of methyl (8S,9R,13R,14R)-4,4,8,9,13-pentamethyl-20(10 → 9)-abeo-ent-isocopal-5(10),11(12)-dien-15-oate - a diterpenoid with the ent-verrucosin A/B skeleton has been performed by electrophilic isomerization of methyl 12α-hydroxy-ent-isocopal-13(16)-en-15-oate. The structure and stereochemistry of the synthesized compound have been established on the basis of spectroscopic data. |
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| Cuvinte-cheie biomimetic synthesis, diterpenoids, Isomerization, Verrucosin A |
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