| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 184 0 |
 SM ISO690:2012GELMBOLDT, Vladimir, ANISIMOV, Vladimir, FONARI, Marina. Interaction between hydrofluorosilicic acid and 1,10-phenanthroline: Hydrolytic stability of chelate complexes of silicon tetrafluoride with bidentate N-donors. In: Russian Journal of Inorganic Chemistry, 2016, nr. 7(61), pp. 822-825. ISSN 0036-0236. DOI: https://doi.org/10.1134/S0036023616070056 |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
 Russian Journal of Inorganic Chemistry |
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| Numărul 7(61) / 2016 / ISSN 0036-0236 /ISSNe 1531-8613 | ||||||
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| DOI:https://doi.org/10.1134/S0036023616070056 | ||||||
| Pag. 822-825 | ||||||
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| Rezumat | ||||||
Hexafluorosilicate (LH2)SiF6 and the cis-[SiF4(L)] chelate complex characterized by 19F NMR are products of reaction between hydrofluorosilicic acid and 1,10-phenanthroline (L). XRD findings show that the structure of (LH2)SiF6 is stabilized by NH···F hydrogen bonds (N···F 2.618(4), 2.676(4) Å) and CH···F contacts. The relative resistance of the cis-[SiF4(L)] complex to hydrolysis is associated with the chelate effect. |
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| Cuvinte-cheie 1, 10-phenanthroline, 19F NMR, Chelate complex, Chelate effects, Hydrolytic stability, Products of reaction, Relative resistance, Silicon tetrafluoride |
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