Modeling of the kinetics of fluorine sorption onto modified trepel
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ZELENTSOV, Veaceslav, DATSKO, Tatiana. Modeling of the kinetics of fluorine sorption onto modified trepel. In: Conference on Applied and Industrial Mathematics: CAIM 2018, 20-22 septembrie 2018, Iași, România. Chișinău, Republica Moldova: Casa Editorial-Poligrafică „Bons Offices”, 2018, Ediţia a 26-a, pp. 55-56. ISBN 978-9975-76-247-2.
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Conference on Applied and Industrial Mathematics
Ediţia a 26-a, 2018
Conferința "Conference on Applied and Industrial Mathematics"
Iași, România, Romania, 20-22 septembrie 2018

Modeling of the kinetics of fluorine sorption onto modified trepel


Pag. 55-56

Zelentsov Veaceslav, Datsko Tatiana
 
Institute of Applied Physics
 
 
Disponibil în IBN: 31 mai 2022


Rezumat

The application of kinetic models of pseudo _rst and second order for the description of experimental kinetic data related to the adsorption of uorine ions on trepel modi_ed by aluminum compounds (TMA) is discussed in this work. The pseudo-_rst-order kinetic model is expressed as [1]: dat dt = k1(am - at) (1) Integrating within the boundary conditions t = 0 to t =  t and att = 0 to at = am gives the linearized form as ln (am - at) = ln am - k1t (2) The pseudo-second order Mackay and Ho model [2] is expressed as dat dt = k1(am - at)2 (3) Rearranging and integrating Eq. (3) with respect to the boundary conditions t = 0 to t = t and at = 0 to at = am gives the linearized form as t at = 1 k2 a2 m + t am (4) where am and at[mmol=g] are the the amounts of uoride ions adsorbed at equilibrium at time t, respectively; k1[min-1] is the pseudo-_rst-order rate constant and k2[mmol=(g min] is the rate constant of the pseudo-second order kinetics. Employing the linearized form of pseudo-_rst-order model (ln (am - at) = f(t), Eq. (2)) and linearized form of pseudo-second-order model (t=at, versus contact time (t), Eq. (4)) we determined the constants k1; k2, and am values using the slopes and intercept points of the linear plots. The results are illustrated in Table.1.